Citation: Lu LIU, Abaid Ullah Malik, Mou-Hai SHU. Syntheses, Crystal Structures and Fluorescence Properties of Four Coordination Polymers Based on Enantiomeric 2-(4-Carboxyphenyl)-4, 5-dihydrothiazole-4-carboxylic Acid Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 567-578. doi: 10.14102/j.cnki.0254-5861.2011-2515 shu

Syntheses, Crystal Structures and Fluorescence Properties of Four Coordination Polymers Based on Enantiomeric 2-(4-Carboxyphenyl)-4, 5-dihydrothiazole-4-carboxylic Acid Ligands

School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China

Corresponding author: Mou-Hai SHU, mhshu@sjtu.edu.cn
Received Date: 27 May 2019
Accepted Date: 20 June 2019

Fund Project: the National Natural Science Foundation of China 21271129

Figures(10)

A pair of enatiomerically pure ligands, (R-)/(S-)2-(4-carboxyphenyl)-4, 5-dihydrothiazole-4-carboxylic acid (H₂L^R & H₂L^S), have been synthesized by the reactions of 4-cyanobenzoic acid with L- and D-cysteine, respectively. Four coordination polymers have been prepared from the ligands and structurally determined by single-crystal X-ray diffraction analysis. Complexes 1R and 1S ([NiL(Py)(H₂O)]⋅H₂O, for 1R, L = (L^R)^2-; for 1S, L = (L^S)^2-) exhibit chiral helical one-dimensional chains, and complexes 2R and 2S ({[ZnL₂(H₂O)₃]⋅CH₃CN}_n, for 2R L = (L^R)^2-, for 2S L = (L^S)^2-) are two-dimensional sheets. Luminescent and chir-optical properties have been investigated and compared with the free ligands. The complexes have blue-shift in luminescence spectrum compared with the free ligands.
- coordination polymer,
- crystal structure,
- chiral ligand,
- fluorescence
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