Citation: Meng YU, Jian-Mei HU, Yong WANG. Synthesis and Characterization of a Terpyridine Ligand and Its Interactions with Selected Metal Ions[J]. Chinese Journal of Structural Chemistry, ;2020, 39(4): 783-792. doi: 10.14102/j.cnki.0254-5861.2011-2498 shu

Synthesis and Characterization of a Terpyridine Ligand and Its Interactions with Selected Metal Ions

Hubei Key Laboratory of Drug Synthesis and Optimization, Jingchu University of Technology, Jingmen, Hubei 444800, China

Corresponding author: Yong WANG, wangyong198711@yahoo.com
Received Date: 25 December 2018
Accepted Date: 9 April 2019

Fund Project: the Science and Technology Research Project of Hubei Provincial Department of Education Q20194301the Cultivating Scientific Research Project of Jingchu University of Technology PY201901

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In this work, a terpyridine ligand L, (4΄-phenyl-2,2΄:6΄,2΄΄-terpyridine), was synthesized and fully characterized. Interactions of the ligand with selected metal ions like Cu(Ⅱ), Fe(Ⅲ), Pb(Ⅱ), Fe(Ⅱ), Cr(Ⅲ), Cd(Ⅱ), Co(Ⅱ), Zn(Ⅱ), Ni(Ⅱ) and Mn(Ⅱ) were investigated. Compared to ligand L, only Fe(Ⅱ) and Pb(Ⅱ) ions show new band in electronic absorption spectroscopy. Fluorescent spectroscopy indicates that Zn(Ⅱ) and Cd(Ⅱ) ions enhance the emission intensity of ligand L, and other selected ions quench emission intensity. To explore how Fe(Ⅱ) ion interacts with ligand L, Fe(L)-based complex 1 was synthesized, spectroscopic studies and single-crystal X-ray diffraction analysis. This implies ligand L has an excellent selectivity for Zn(Ⅱ) and Cd(Ⅱ) ions.
- Fe(Ⅱ) ion,
- molecular structure,
- terpyridine,
- electronic absorption spectroscopy,
- fluorescent spectroscopy
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