Citation: Xu LIU, Teng TENG, Lei-Xiang GU, Li-Chao GE, Wen HE, Hui-Yong LIAO, Yi-Jun CHE, Chong-Yao LIANG, Yuan-Yuan DAN, Li-Zhuang CHEN. Facile Synthesis of Layered Sodium Manganese Oxide for Application in Asymmetric Supercapacitor[J]. Chinese Journal of Structural Chemistry, ;2020, 39(4): 756-764. doi: 10.14102/j.cnki.0254-5861.2011-2496 shu

Facile Synthesis of Layered Sodium Manganese Oxide for Application in Asymmetric Supercapacitor

Xu LIU ^{a, #} ,
Teng TENG ^{a, #} ,
Lei-Xiang GU ^a ,
Li-Chao GE ^a ,
Wen HE ^a ,
Hui-Yong LIAO ^a ,
Yi-Jun CHE ^a ,
Chong-Yao LIANG ^a ,
Yuan-Yuan DAN ^{a, b,,} ,
Li-Zhuang CHEN ^{a, b,,}

a.
School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China
b.
Marine Equipment and Technology Institute, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China

Corresponding author: Yuan-Yuan DAN, danyy@just.edu.cn Li-Zhuang CHEN, clz1977@sina.com
Received Date: 12 June 2019
Accepted Date: 26 November 2019

Figures(5)

Layered sodium manganese oxides (LSMOs), with two-dimensional channels for ion diffusion, have been regarded as the promising electrode materials in the application of asymmetric supercapacitors (ASCs). In this work, the layered Na_0.5Mn₂O₄·1.5H₂O was synthesized through a facile hydrothermal method by controlling the molar ratio of sodium and manganese. When the molar ratio of sodium to manganese is 3:1, Na_0.5Mn₂O₄·1.5H₂O has shown the best capacitance of 369 F/g with current density of 0.5 A/g, and maintained a capacitance of 265 F/g after 2000 cycles. The asymmetric supercapacitor consists of the sodium manages oxides as the positive electrode and active carbon (AC) as the negative electrode in 1 mol/L Na₂SO₄ solution. The voltage of the asymmetric supercapacitor has been expanded to 0~2 V with an energy density of 10.13 Wh/kg at a power density of 500 W/kg based on the total weight of both active electrode materials when the mass ratio of AC to Na_0.5Mn₂O₄·1.5H₂O was 3:1.
- layered sodium manganese oxides,
- asymmetric supercapacitor,
- electrochemical performance
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