Citation: Wei-Sheng LIN, Jian-Gen HUANG, Yun-Xiang WEN, Hui LUO, Wen-Tong CHEN. Photophysical Performance and Energy Transfer Mechanism of a 1-D Chain-like Complex[J]. Chinese Journal of Structural Chemistry, ;2020, 39(4): 747-755. doi: 10.14102/j.cnki.0254-5861.2011-2486 shu

Photophysical Performance and Energy Transfer Mechanism of a 1-D Chain-like Complex

Wei-Sheng LIN ^a ,
Jian-Gen HUANG ^b,, ,
Yun-Xiang WEN ^b ,
Hui LUO ^b ,
Wen-Tong CHEN ^{a, b, c,,}

a.
Department of Ecological and Resources Engineering, Fujian Key Laboratory of Eco-industrial Green Technology, Wuyi University, Wuyishan, Fujian 354300, China
b.
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Humic Acid Utilization Engineering Research Center of Jiangxi Province, Jinggangshan University, Ji'an, Jiangxi 343009, China
c.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Jian-Gen HUANG, hjg0468@163.com Wen-Tong CHEN, wtchen_2000@aliyun.com

Dedicated to Professor Jin-Shun Huang on the occasion of his 80th birthday

Received Date: 3 June 2019
Accepted Date: 26 November 2019

Fund Project: the NNSFC 21361013the NNSFC 31460488NSF of Fujian 2018J01447Jiangxi Provincial Department of Education's Item of Science and Technology GJJ170637the Open Foundation 20180008

Figures(8)

By means of solvothermal reactions, a novel lanthanide-mercury compound, {[Ho(IA)₃(H₃O)₂]_2n[2n(HgCl₄)][n(HgCl₅)]}·3nH₃O·nH₂O (1, HIA = isonicotinc acid) was prepared and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in the C2/c space group of monoclinic system with a = 24.2147(5), b = 20.8106(4), c = 15.3060(3) Å, β = 128.326(2)°, V = 6050.8(2) Å³, C₃₆H₄₅Cl₁₃Hg₃Ho₂N₆O₂₀, M_r = 2274.26, Z = 4, D_c = 2.497 g/cm³, μ(MoKα) = 10.817 mm^–1 and F(000) = 4232. It exhibits a one-dimensional (1-D) chain-like structure. Solid-state photoluminescence measurement shows that it displays brown light emission bands. These emission bands originate from the characteristic emissions of the 4f electrons intrashell transitions of ⁵S₂ → ⁵I₈ and ⁵F₅ → ⁵I₈ of the holmium(Ⅲ) ions in 1. The photoluminescence emission energy transfer mechanism is elucidated by the energy level diagrams of the holmium(Ⅲ) ions and isonicotinic acid ligand. Complex 1 has CIE chromaticity coordinates of (0.4361, 0.4992). Solid-state UV/Vis diffuse reflectance spectra reveal that it possesses wide optical band gap of 4.94 eV.
- chromaticity coordinate,
- energy transfer,
- isonicotinc acid,
- lanthanide,
- Photoluminescence
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