Citation: Yao ZHAO, Jun-Hua YOU, Wen-Quan LV, Ming FANG. Synthesis and Absorption Properties of Leaf-like Nd₂Cu₂O_4+δ via a Coordination Complex Method with [NdCu(3,4-pdc)₂(OAc)(H₂O)₅]·6.5H₂O Precursor[J]. Chinese Journal of Structural Chemistry, ;2020, 39(4): 737-746. doi: 10.14102/j.cnki.0254-5861.2011-2484 shu

Synthesis and Absorption Properties of Leaf-like Nd₂Cu₂O_4+δ via a Coordination Complex Method with [NdCu(3,4-pdc)₂(OAc)(H₂O)₅]·6.5H₂O Precursor

Yao ZHAO ^a ,
Jun-Hua YOU ^a,, ,
Wen-Quan LV ^b ,
Ming FANG ^c,,

a.
School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China
b.
Institute of Modern Physics, Chinese Academy of Sciences (CAS), Lanzhou 730000, China
c.
Department of Chemistry, Hebei Normal University of Science & Technology, Qinhuangdao 066004, China

Corresponding author: Jun-Hua YOU, youjunhua168@163.com Ming FANG, fangmingchem@163.com
Received Date: 3 June 2019
Accepted Date: 9 September 2019

Fund Project: Liaoning Province College Innovative Talents Fund Project LCR2018016the Natural Science Foundation of Liaoning Province 2019-MS-244

Figures(6)

Nd₂Cu₂O_4+δ nanosheets were synthesized via coordination complex method (CCM) by using [NdCu(3,4-pdc)₂(OAc)(H₂O)₅]·6.5H₂O (1,3,4-pdc = 3,4-pyridinedicarboxylic acid) as the precursor. Compared to the particles prepared by SSM (simple solution method), Nd₂Cu₂O_4+δ prepared by CCM showed leaf-like morphology composed of nanosheets with an average thickness of 50~80 nm and a BET surface area up to 17.9 m²/g. The Nd₂Cu₂O_4+δ samples exhibit selective adsorption towards malachite green (MG) with significant Q_m (maximum adsorption capacity) values reaching up 1.55 g/g at room temperature, and the thermodynamic parameters of adsorption process were obtained. In addition, the properties of selective adsorption of the prepared samples were investigated by temperature change tests.
- Nd₂Cu₂O_4+δ,
- coordination-complex method,
- simple solution method,
- selective adsorption,
- malachite green
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通讯作者: 陈斌, bchen63@163.com

Synthesis and Absorption Properties of Leaf-like Nd₂Cu₂O_4+δ via a Coordination Complex Method with [NdCu(3,4-pdc)₂(OAc)(H₂O)₅]·6.5H₂O Precursor