Citation: Yu LI, Jiang WU, Jin-Zhong GU, Wen-Da QIU, An-Sheng FENG. Temperature-dependent Syntheses of Two Manganese(Ⅱ) Coordination Compounds Based on an Ether-bridged Tetracarbolylic Acid[J]. Chinese Journal of Structural Chemistry, ;2020, 39(4): 727-736. doi: 10.14102/j.cnki.0254-5861.2011-2483 shu

Temperature-dependent Syntheses of Two Manganese(Ⅱ) Coordination Compounds Based on an Ether-bridged Tetracarbolylic Acid

Yu LI ^a ,
Jiang WU ^b ,
Jin-Zhong GU ^c,, ,
Wen-Da QIU ^a,, ,
An-Sheng FENG ^a

a.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
b.
Key Laboratory for Tibet Plateau Phytochemistry of Qinghai Province, School of Pharmacy, Qinghai University for Nationalities, Xining 810007, China
c.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Jin-Zhong GU, gujzh@lzu.edu.cn Wen-Da QIU, 2016100035@gditc.edu.cn
Received Date: 1 June 2019
Accepted Date: 21 October 2019

Fund Project: Guangdong Province Higher Vocational Colleges & Schools Pearl River Scholar Funded Scheme 2015Guangdong Province Higher Vocational Colleges & Schools Pearl River Scholar Funded Scheme 2018the Natural Science Foundation of Guangdong Province 2016A030313761the Pearl River Scholar Foundation of Guangdong Industry Polytechnic RC2015-001the Opening Foundation of MOE Key Laboratory of MOE Key Laboratory of Bioinorganic and Synthetic Chemistry School of Chemistry Sun Yat-Sen University 2016Innovation Team Project on University of Guangdong Province 2017GKCXTD001Science and Technology Planning Project of Guangzhou 201904010381the Science and Technology Plan of Qinghai Province 2018-ZJ-919

Figures(11)

0D dinuclear manganese(Ⅱ) coordination compound and 1D chain manganese(Ⅱ) coordination polymer, namely [Mn₂(μ-L)(phen)₄]·4H₂O (1) and {[Mn₂(μ₅-L)(phen)₂]·H₂O}_n (2), have been constructed hydrothermally using H₄L (H₄L = 2,3,3΄,4΄-diphenyl ether tetracarboxylic acid), phen (phen = 1,10-phenanthroline), and manganese chloride at 120 and 160 ℃, respectively. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses (TGA), and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that two compounds crystallize in the triclinic or monoclinic system, space group P\begin{document}$ \overline 1 $\end{document} or P2₁/c. Compound 1 discloses a discrete dimeric structure, which is assembled into a 3D supramolecular framework through O–H∙∙∙O hydrogen bond. Compound 2 has a chain structure. Structural differences between compounds 1 and 2 are attributed to the different reaction temperature. Magnetic studies for compound 2 demonstrate an antiferromagnetic coupling between the adjacent Mn(Ⅱ) centers.
- crystal structure,
- manganese coordination compound,
- tetracarboxylic acid,
- magnetic properties
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