Citation: Qian-Ting XU, Man-Man CHEN, Shen-Jing JI, Sheng-Ping GUO. Diverse Hf-Q Chains Existing in the Ternary Eu-Hf-Q (Q = S, Se) System[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 437-442. doi: 10.14102/j.cnki.0254-5861.2011-2474 shu

Diverse Hf-Q Chains Existing in the Ternary Eu-Hf-Q (Q = S, Se) System

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

Corresponding author: Sheng-Ping GUO, spguo@yzu.edu.cn
Received Date: 28 May 2019
Accepted Date: 26 July 2019

Fund Project: NNSFC 21771159State Key Laboratory of Structural Chemistry 20190020

Figures(3)

Two ternary Eu-Hf-Q (Q = S, Se) chalcogenides, EuHfSe₃ (1) and Eu₅Hf₃S₁₂ (2), have been synthesized by a facile solid state routine and structurally characterized by single-crystal X-ray diffraction technique. They crystallize in the orthorhombic space group Pnma (1) or hexagonal P62m (2), and diverse Hf-Q chains exist in their 3D structures. The electronic structure of 1 is also calculated according to density functional theory.
- rare-earth chalcogenide,
- solid-state synthesis,
- crystal structure,
- theory calculation
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