Citation: Bin WANG, Ting-Hai MU, Jun-Rong LING, You-Fu ZHOU, Wen-Tao XU, He LIN. Doping Effect of Bi³⁺ on the Properties of YAG: Ce³⁺, Mn²⁺ Phosphor Ceramics for Warm WLEDs[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 511-518. doi: 10.14102/j.cnki.0254-5861.2011-2452 shu

Doping Effect of Bi³⁺ on the Properties of YAG: Ce³⁺, Mn²⁺ Phosphor Ceramics for Warm WLEDs

Bin WANG ^{a, b} ,
Ting-Hai MU ^{a, b} ,
Jun-Rong LING ^{a, b} ,
You-Fu ZHOU ^a,, ,
Wen-Tao XU ^a ,
He LIN ^a

a.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: You-Fu ZHOU, yfzhou@fjirsm.ac.cn
Received Date: 9 May 2019
Accepted Date: 27 June 2019

Fund Project: the grants of CAS Priority Research program XDB20010300the grants of CAS Priority Research program XDA21010204Natural Science Foundation of Fujian Province 2017H0048

Figures(11)

A series of Bi³⁺-doped YAG: Ce³⁺, Mn²⁺ ceramics was synthesized successfully by gel-casting method and structurally characterized by XRD and SEM. The doping effect and related mechanism of Bi³⁺ upon the luminescent property were studied. It can be assigned to the energy transfer of multipolar interaction from Bi³⁺ to Ce³⁺, leading to the improvement of emission intensity about 58% for 0.0001 Bi³⁺ and 0.05 Mn²⁺ doping. In addition, the emission is significantly red-shifted with the peak at 590 nm for the Y_2.9939Ce_0.006Bi_0.0001Al_4.96Mn_0.02Si_0.02O₁₂ ceramic specimen with in-line transmittance 81.6% at 1100 nm. The LED module assembled from Y_2.9939Ce_0.006Bi_0.0001Al_4.96Mn_0.02Si_0.02O₁₂ ceramic owns correlated color temperature (CCT) of 3960 K and luminous efficiency (LE) of 92 lm/W, implying that doping Bi³⁺ shows a good sensitization effect in the YAG: Ce³⁺, Mn²⁺ ceramic system and further serving as an attracting phosphor candidates for warm WLEDs applications.
- Bi³⁺ doping,
- gel-casting method,
- phosphor ceramic,
- microstructure,
- luminescent property
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Doping Effect of Bi3+ on the Properties of YAG: Ce3+, Mn2+ Phosphor Ceramics for Warm WLEDs

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Doping Effect of Bi³⁺ on the Properties of YAG: Ce³⁺, Mn²⁺ Phosphor Ceramics for Warm WLEDs