Citation: Ru-Ru CHEN, Wei-Guang YANG, Min-Na CAO, Hong-Fang LI. Synthesis and Crystal Structure of a New Noble Metal-containing Supramolecular Self-assembly with Decamethylcucurbit[5]uril[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 535-542. doi: 10.14102/j.cnki.0254-5861.2011-2440 shu

Synthesis and Crystal Structure of a New Noble Metal-containing Supramolecular Self-assembly with Decamethylcucurbit[5]uril

Ru-Ru CHEN ^{a, b} ,
Wei-Guang YANG ^{a, b} ,
Min-Na CAO ^b,, ,
Hong-Fang LI ^b,,

a.
College of Chemistry, Fuzhou University, Fuzhou 350002, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Min-Na CAO, mncao@fjirsm.ac.cn Hong-Fang LI, hongfangli@fjirsm.ac.cn
Received Date: 5 May 2019
Accepted Date: 20 July 2019

Fund Project: the National Key R & D Program of China 2017YFA0206800the National Key R & D Program of China 2016YFB0600903the NSFC 21573238the NSFC 21571177the NSFC 21520102001Key Research Program of Frontier Science, CAS QYZDJ-SSW-SLH045"Strategic Priority Research Program" of the Chinese Academy of Sciences XDB20000000

Figures(6)

A new supramolecular self-assembly [Li(H₂O)₂]₂[(H₂O@Me₁₀CB[5])][PtCl₆]·7H₂O (1, Me₁₀CB[5] = decamethylcucurbit[5]uril), has been successfully constructed with Me₁₀CB[5] and [PtCl₆]^2- anion in the presence of lithium cation (Li⁺). Single-crystal X-ray diffraction study reveals that compound 1 crystallizes in monoclinic space group P2₁/n with a = 11.1681(18), b = 28.5425(4), c = 18.9342(3) Å, β = 99.0143(15)°, V = 5961.02(16) Å³, Z = 4, F(000) = 3224, μ = 2.714 mm^-1, R = 0.0470 and wR = 0.1076 (I > 2σ(I)). In the supramolecular self-assembly, two of the portal carbonyl oxygen atoms of Me₁₀CB[5] are coordinated to Li⁺ cation, yielding a "half-open" molecular capsule. Then adjacent molecular capsules are connected with each other through hydrogen-bonding to form a one-dimensional (1D) supramolecular chain structure. The [PtCl₆]^2- anions are fixed on one side of the 1D supramolecular chain through supramolecular interactions. The thermal stability, electronic valence and morphology of compound 1 are also investigated.
- decamethylcucurbit[5]uril,
- noble metal,
- supramolecular self-assembly,
- crystal structure
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