Citation: Meng-Ye XU, Zhi-Qin WANG, Yu-Ling WANG, Qing-Yan LIU. A Luminescent Tb(III)-4, 4′, 4′′-nitrilotribenzoate Compound with a Three-dimensional Structure[J]. Chinese Journal of Structural Chemistry, ;2020, 39(1): 126-131. doi: 10.14102/j.cnki.0254-5861.2011-2425 shu

A Luminescent Tb(III)-4, 4′, 4′′-nitrilotribenzoate Compound with a Three-dimensional Structure

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: Qing-Yan LIU, qyliuchem@jxnu.edu.cn
Received Date: 25 April 2019
Accepted Date: 18 July 2019

Fund Project: the National Natural Science Foundation of China 21661014the National Natural Science Foundation of China 21861020Natural Science Foundation of Jiangxi Province 20181BAB203001the innovation fund for the graduate student YJS2018059

Figures(6)

A coordination polymer of [Tb(ntb)]_n (1) based on 4, 4′, 4′′-nitrilotribenzoate ligand (ntb^3–) was synthesized. Compound 1 crystallizes in the monoclinic system, space group C2/c with a = 13.7318(4), b = 27.5628(9), c = 5.4046(2) Å, β = 111.142(3)°, V = 1907.88(12) Å³, Z = 4, C₂₁H₁₂NO₆Tb, M_r = 533.24, D_c = 1.856 g/cm³, μ = 3.745 mm^–1, F(000) = 1032, the final R = 0.0184 and wR = 0.0456 for 1883 observed reflections with I > 2σ(I). In compound 1, the eight-coordinated Tb(III) atoms are bridged by the carboxylate groups of ntb^3– ligands to generate a one-dimensional Tb-carboxylate chain, which is further linked by the ntb^3– ligands to form a three-dimensional structure. Compound 1 exhibits characteristic Tb(III) luminescent emissions in the solid state.
- Terbium coordination polymer,
- 4, 4΄, 4΄΄-nitrilotribenzoate,
- luminescence,
- crystal structure
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