Citation: Nan DING, Zhong-Yi LIU, Rin-Min CHEN, Yi-Lin BO, Xiu-Guang WANG, Xiao-Jun ZHAO, En-Cui YANG. A New Pillared-layer Framework with Co^Ⅱ 4-Triazole Magnetic Layer Exhibiting Strong Spin-frustration[J]. Chinese Journal of Structural Chemistry, ;2020, 39(3): 519-525. doi: 10.14102/j.cnki.0254-5861.2011-2423 shu

A New Pillared-layer Framework with Co^Ⅱ 4-Triazole Magnetic Layer Exhibiting Strong Spin-frustration

College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-organic Hybrid Functional Material Chemistry, Tianjin Normal University, Tianjin 300387, China

Corresponding author: En-Cui YANG, encui_yang@163.com
Received Date: 19 April 2019
Accepted Date: 16 July 2019

Fund Project: NNSFC 21303121the Program for Innovative Research Team at University of Tianjin TD13-5074Innovation Program of Tianjin University students 201810065338

Figures(4)

One new coordination polymer, [Co₄(H₂O)₄(μ₃-OH)₂(atz)₂(L)]_n (1), was solvothermally prepared by the reaction of 3-amino-1, 2, 4-triazole (Hatz), 4, 8-disulfonyl-2, 6-naphthalenedicarboxylic acid (H₄L) and Co^Ⅱ salt. It crystallizes in monoclinic system, space group P2₁/c with a = 10.4454(7), b = 12.2214(8), c = 10.0818(7) Å, β = 102.284(7), V = 1257.56(15) Å³, D_c = 2.325 g/cm³, M_r = 880.24, Z = 2, F(000) = 880, μ = 2.859 mm^-1, the final R = 0.0426 and wR = 0.0822 for 5526 observed reflections with I > 2σ(I). Structural analyses indicate that 1 exhibits a three-dimensional (3D) pillared-layer framework with triazolate extended Co₄^Ⅱ layers supported by rigid L^4- connectors. Magnetically, complex 1 displays strong spin-frustrated antiferromagnetism due to the triangular magnetic lattice and cooperative antiferromagnetic couplings mediated by quadruple heterobridges.
- pillared-layer framework,
- 1,2,4-triazole,
- spin-frustration
1. [1]
  Espallargas, G. M.; Coronado, E. Magnetic functionalities in MOFs: from the framework to the pore. Chem. Soc. Rev. 2018, 47, 533–557. doi: 10.1039/C7CS00653E
2. [2]
  Weng, D. F.; Wang, Z. M.; Gao, S. Framework-structured weak ferromagnets. Chem. Soc. Rev. 2011, 40, 3157–3181. doi: 10.1039/c0cs00093k
3. [3]
  Miller, J. S. Magnetically ordered molecule-based and materials. Chem. Soc. Rev. 2011, 40, 3266–3296. doi: 10.1039/c0cs00166j
4. [4]
  Zeng, Y. F.; Hu, X.; Liu, F. C.; Bu, X. H. Aziso mediated systems showing different magnetic behaviors. Chem. Soc. Rev. 2009, 38, 469–480. doi: 10.1039/B718581M
5. [5]
  Wang, H. S.; Yang, F. J.; Long, Q. Q.; Huang, Z. Y.; Chen, W.; Pan, Z. Q. Syntheses, crystal structures, and magnetic properties of a family of heterometallic octanuclear [Cu₆Ln₂] (Ln = Dy(Ⅲ), Tb(Ⅲ), Ho(Ⅲ), Er(Ⅲ), and Gd(Ⅲ)) complexes. New J. Chem. 2017, 41, 5884‒5892. doi: 10.1039/C7NJ00459A
6. [6]
  Wang, H. S.; Yao L.; Pan, M.; Zhong, W. D.; Xu, W.; Pan, Z. Q. Synthesis, crystal structure and magnetic properties of a heptanuclear Mn complex with 2-(hydroxymethyl)pyridine and 1, 1, 1-tris(hydroxymethyl)ethane mixed-ligands. Chin. J. Inorg. Chem. 2016, 32, 153‒160.
7. [7]
  Ouellette, W.; Jones, S.; Zubieta, J. Solid state coordination chemistry of metal-1, 2, 4-triazolates and the related metal-4-pyridyltetrazolates. CrystEngComm. 2011, 13, 4457–4485. doi: 10.1039/c0ce00919a
8. [8]
  Liu, X. Y.; Qu, X. N.; Zhang, S.; Ke, H. S.; Yang, Q.; Shi, Q.; Wei, Q.; Xie, G.; Chen, S. High-performance energetic characteristics and magnetic properties of a three-dimensional cobalt(Ⅱ) metal-organic framework assembled with azido and triazole. Inorg. Chem. 2015, 54, 23, 11520–11525.
9. [9]
  Ouellette, W.; Galán-Mascarós, J. R.; Dunbar, K. R.; Zubieta, J. Hydrothermal synthesis and structure of a three-dimensional cobalt(Ⅱ) triazolate magnet. Inorg. Chem. 2006, 45, 1909–1911. doi: 10.1021/ic051992i
10. [10]
  Ouellette, W.; Prosvirin, A. V.; Valeich, J.; Dunbar, K. R.; Zubieta, J. Hydrothermal synthesis, structure chemistry, and magnetic properties of material of the M^Ⅱ/triazolate/anion family, where M^Ⅱ = Mn, Fe, and Ni. Inorg. Chem. 2007, 46, 9067–9082. doi: 10.1021/ic700790h
11. [11]
  Liu, Z. Y.; Zhao, H.; Song, W. X.; Wang, X. G.; Liu, Z. Y.; Zhao, X. J.; Yang, E. C. A dynamic microporous magnet exhibiting room-temperature thermal hysteresis, variable magnetic ordering temperatures and highly selective adsorption for CO₂. J. Mater. Chem. C 2019, 7, 218. doi: 10.1039/C8TC03356K
12. [12]
  Zhang, C.; Liu, Z. Y.; Liu, N.; Zhao, H.; Yang, E. C.; Zhao, X. J. Different magnetic responses observed in Co₄^Ⅱ, Co₃^Ⅱ and Co₁^Ⅱ-based MOFs. Dalton Trans. 2016, 45, 11864–11875. doi: 10.1039/C6DT01587E
13. [13]
  Sarma, D.; Srivastava, V.; Natarajan, S. Aza-heterocylic ligand assisted assembly of new cobalt MOFs with pcu and graphite related structures. Dalton Trans. 2012, 41, 4135–4145. doi: 10.1039/c2dt11993e
14. [14]
  Yang, E. C.; Liu, Z. Y.; Shi, X. J.; Liang, Q. Q.; Zhao, X. J. Two 3D triazolate-tricarboxylate-bridged Cu^Ⅱ frameworks by one-pot hydrothermal synthesis exhibiting spin-canted antiferromagnetism and strong antiferromagnetic couplings. Inorg. Chem. 2010, 49, 7969–7975. doi: 10.1021/ic100880j
15. [15]
  Yang, E. C.; Liu, Z. Y.; Liu, Y. T.; Li, L. L.; Zhao, X. J. Co-ligand-directed structural and magnetic diversities in an anisotropic Co^Ⅱ-triazolate system. Dalton Trans. 2011, 40, 8132–8139. doi: 10.1039/c1dt10394f
16. [16]
  Yang, E. C.; Ding, B.; Liu, Z. Y.; Yang, Y. L.; Zhao, X. J. Structural transformation from a discrete Cu₄^Ⅱ cluster to two extended Cu₄^Ⅱ + Cu₁^Ⅱ chain-based three-dimensional frameworks by changing the spacer functionality: synthesis, crystal structures, and magnetic properties. Cryst. Growth Des. 2012, 12, 1185–1192. doi: 10.1021/cg2011666
17. [17]
  Liu, Z. Y.; Yang, E. C.; Li, L. L.; Zhao, X. J. A reversible SCSC transformation from a blue metamagnetic framework to a pink antiferromagnetic ordering layer exhibiting concomitant solvatochromic and solvatomagnetic effects. Dalton Trans. 2012, 41, 6827–6832. doi: 10.1039/c2dt30245d
18. [18]
  Liu, Z. Y.; Ding, B.; Yang, E. C.; Zhao, X. J. A (3, 4, 14)-connected framework with various distorted triangular magnetic lattices exhibiting field-induced metamagnetism, spin competition and spin reorientation. Dalton Trans. 2012, 41, 9611–9614. doi: 10.1039/c2dt30496a
19. [19]
  Yang, E. C.; Liu, Z. Y.; Zhang, C. H.; Yang, Y. L.; Zhao, X. J. Structural diversity directed by switchable coordination of substitute groups in a ternary Cu^Ⅱ-triazole-sulfoisophthalate self-assembly system: synthesis, crystal structures and magnetic behavior. Dalton Trans. 2013, 42, 1581–1590. doi: 10.1039/C2DT31935G
20. [20]
  Liu, Q. Y.; Wang, W. F.; Wang, L. Y.; Shan, Z. M.; Wang, M. S.; Tang, J. K. Diversity of lanthanide(Ⅲ)-organic extended frameworks with a 4, 8-disulfonyl-2, 6-naphthalenedicarboxylic acid ligand: syntheses, structure, and magnetic and luminescent properties. Inorg. Chem. 2012, 51, 2381–239. doi: 10.1021/ic2023727
21. [21]
  Oxford Diffraction Ltd, SCALE3 ABSPACK: Empirical Absorption Correction. CrysAlis-Software package. Oxford 2006.
22. [22]
  Agilent Technologies, CryAlisPro, Oxfordshire, England 2010.
23. [23]
  Sheldrick, G. M. ShelXT. Göttingen University, Göttingen, Germany 2015.
24. [24]
  Sheldrick, G. M. ShelXL. Göttingen University: Göttingen, Germany 2015.
25. [25]
  Li, Y. M.; Lun, H. J.; Xiao, C. Y.; Xu, Y. Q.; Wu, L.; Yang, J. H.; Niu, J. Y.; Xiang, S. C. A bilayer triangular lattice with crown-like Co₇ spin cluster SBUs exhibiting high spin frustration. Chem. Commun. 2014, 50, 8558–8560 doi: 10.1039/C4CC02910K
26. [26]
  Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. New York: Wiley 1978.
27. [27]
  Kurmoo, M. Magnetic metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1353–1379. doi: 10.1039/b804757j
28. [28]
  Rueff, J.; Masciocchi, N.; Rabu, P.; Sironi, A.; Skoulios, A. Structure and magnetism of a polycrystalline transition metal soap-Co^Ⅱ[OOC(CH₂)₁₀COO](H₂O)₂. Eur. J. Inorg. Chem. 2001, 11, 585–591.
29. [29]
  Shores, M. P.; Nytko, E. A.; Bartlett, B. M.; Nocera, D. G. A structurally perfect S = 1/2 Kagomé antiferromagnet. J. Am. Chem. Soc. 2005, 127, 13462–13463. doi: 10.1021/ja053891p
1. [1]
  Shiqi Xu , Zi Ye , Shuang Shang , Fengge Wang , Huan Zhang , Lianguo Chen , Hao Lin , Chen Chen , Fang Hua , Chong-Jing Zhang . Pairs of thiol-substituted 1,2,4-triazole-based isomeric covalent inhibitors with tunable reactivity and selectivity. Chinese Chemical Letters, 2024, 35(7): 109034-. doi: 10.1016/j.cclet.2023.109034
2. [2]
  Jing Wang , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Single-layer crystalline triazine-based organic framework photocatalysts with different linking groups for H2O2 production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100202-100202. doi: 10.1016/j.cjsc.2023.100202
3. [3]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
4. [4]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
5. [5]
  Jia-Cheng Hou , Hong-Tao Ji , Yu-Han Lu , Jia-Sheng Wang , Yao-Dan Xu , Yan-Yan Zeng , Wei-Min He . Sustainable and practical semi-heterogeneous photosynthesis of 5-amino-1,2,4-thiadiazoles over WS₂/TEMPO. Chinese Chemical Letters, 2024, 35(8): 109514-. doi: 10.1016/j.cclet.2024.109514
6. [6]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
7. [7]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
8. [8]
  Yunjia Jiang , Lingyao Wang , Yuanbin Zhang . Anion pillared MOFs for challenging hydrocarbon separations. Chinese Journal of Structural Chemistry, 2024, 43(11): 100374-100374. doi: 10.1016/j.cjsc.2024.100374
9. [9]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
10. [10]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
11. [11]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
12. [12]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
13. [13]
  Hai-Yang Song , Jun Jiang , Yu-Hang Song , Min-Hang Zhou , Chao Wu , Xiang Chen , Wei-Min He . Supporting-electrolyte-free electrochemical [2 + 2 + 1] annulation of benzo[d]isothiazole 1,1-dioxides, N-arylglycines and paraformaldehyde. Chinese Chemical Letters, 2024, 35(6): 109246-. doi: 10.1016/j.cclet.2023.109246
14. [14]
  Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
15. [15]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
16. [16]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
17. [17]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
18. [18]
  Zhenchun Yang , Bixiao Guo , Zhenyu Hu , Kun Wang , Jiahao Cui , Lina Li , Chun Hu , Yubao Zhao . Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production. Chinese Chemical Letters, 2024, 35(8): 109251-. doi: 10.1016/j.cclet.2023.109251
19. [19]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
20. [20]
  Peiyan Zhu , Yanyan Yang , Hui Li , Jinhua Wang , Shiqing Li . Rh(Ⅲ)‐Catalyzed sequential ring‐retentive/‐opening [4 + 2] annulations of 2H‐imidazoles towards full‐color emissive imidazo[5,1‐a]isoquinolinium salts and AIE‐active non‐symmetric 1,1′‐biisoquinolines. Chinese Chemical Letters, 2024, 35(10): 109533-. doi: 10.1016/j.cclet.2024.109533

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(179)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A New Pillared-layer Framework with CoⅡ 4-Triazole Magnetic Layer Exhibiting Strong Spin-frustration

Metrics

通讯作者: 陈斌, bchen63@163.com

A New Pillared-layer Framework with Co^Ⅱ 4-Triazole Magnetic Layer Exhibiting Strong Spin-frustration