Citation: Juan SONG, Bo-Feng DUAN, Jiu-Fu LU, Hong-Guang GE. Three New Lanthanide Coordination Polymers Constructed from 2,6-Bis(pyrazin-2-yl)pyridine-4-carboxylate: Syntheses, Structures and Luminescence[J]. Chinese Journal of Structural Chemistry, ;2020, 39(4): 793-800. doi: 10.14102/j.cnki.0254-5861.2011-2393 shu

Three New Lanthanide Coordination Polymers Constructed from 2,6-Bis(pyrazin-2-yl)pyridine-4-carboxylate: Syntheses, Structures and Luminescence

a.
Shaanxi Key Laboratory of Catalysis, College of Chemical & Environment Science, Shaanxi University of Technology, Hanzhong 723001, China
b.
Mechanical Engineering Training Center, Shaanxi University of Technology, Hanzhong 723001, China

Corresponding author: Juan SONG, sj-528@163.com
Received Date: 2 April 2019
Accepted Date: 4 November 2019

Fund Project: the Key Scientific Research Project of Education Department of Shaanxi Province 17JS027

Figures(3)

Three new lanthanide coordination polymers [Ln(bppc)₂(suc)_0.5(H₂O)]_n·nH₂O (Ln = Eu(1), Ln = Dy(2), Ln = Tb(3), Hbppc = 2,6-bis(pyrazin-2-yl)pyridine-4-carboxylate, H₂suc = succinic acid) have been hydrothermally synthesized and structurally characterized. These compounds are isostructural and crystallize in triclinic \begin{document}$ P\overline 1 $\end{document} space group. The Ln(Ⅲ) ions are eightcoordinated with dodecahedral coordination geometry. Ln(Ⅲ) cations are linked by carboxylate groups from (bppc)^– ligands to form one-dimensional ring chains, which are further connected by the carboxylate groups of (bppc)^– and (suc)^2– ligands to extend a 2D layer structure. These coordination polymers display the characteristic emission bands of Ln(Ⅲ) ions in the solid state.
- lanthanide,
- coordination polymers,
- crystal structure,
- luminescence properties
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沈阳化工大学材料科学与工程学院沈阳 110142