Citation: Bin LI, Wang-Jian FANG, Shu-Qin LIU, He ZHAO, Jian-Jun ZHANG. Two Novel Coordination Polymers with (6, 3) Topology Constructed by an Imidazole-containing Isophthalic Ligand: Syntheses, Structures and Luminescence Properties[J]. Chinese Journal of Structural Chemistry, ;2020, 39(1): 110-117. doi: 10.14102/j.cnki.0254-5861.2011-2388 shu

Two Novel Coordination Polymers with (6, 3) Topology Constructed by an Imidazole-containing Isophthalic Ligand: Syntheses, Structures and Luminescence Properties

Chemistry Department, Dalian University of Technology, Dalian 116024, China

Corresponding author: Shu-Qin LIU, shuqinliu@163.com Jian-Jun ZHANG, zhangjj@dlut.edu.cn
Received Date: 1 April 2019
Accepted Date: 6 June 2019

Fund Project: the National Natural Science Foundation of China 21871038

Figures(7)

Two novel coordination polymers, [Zn(^ImNIPA)(DMSO)]_n (1) and [Cd(^ImNIPA)(DMSO)]_n (2) (H₂^ImNIPA = 5-(6-(1H-imidazol-1-yl)-1, 3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)isophthalic acid, DMSO = dimethylsulfoxide), were prepared under solvothermal conditions through the reactions of Zn²⁺/Cd²⁺ and a new imidazole-containing isophthalic ligand H₂^ImNIPA. The compounds were fully characterized by elemental analysis, FT-IR spectroscopy, powder X-ray diffraction analysis and X-ray single-crystal diffraction analysis. Both 1 and 2 are two-dimensional (2D) coordination layers via the combination of 3-connected metal nodes and ^ImNIPA^2- linker, featuring (6, 3) honeycomb-type topology. In addition, the 2D layers in the two compounds are further extended into 3D supramolecular frameworks via π-π stacking interactions. Finally, the thermal-stability and solid-state luminescence properties of them were also investigated.
- coordination polymer,
- crystal structure,
- π-π stacking interaction,
- luminescence
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