Citation: Ming-Xing YANG, Zhi-Wei YAN, Li-Juan CHEN, Xing-Ye LIN, Shen LIN. Two novel Cobalt(II) /Nickel(II) Metal-organic Coordination Polymers Based on Flexible Polycarboxylic Acids and Rigid Bis(imidazole) Mix Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(1): 147-153. doi: 10.14102/j.cnki.0254-5861.2011-2385 shu

Two novel Cobalt(II) /Nickel(II) Metal-organic Coordination Polymers Based on Flexible Polycarboxylic Acids and Rigid Bis(imidazole) Mix Ligands

College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian 350007, China

Corresponding author: Shen LIN, shenlin@fjnu.edu.cn
Received Date: 29 March 2019
Accepted Date: 11 July 2019

Fund Project: the National Natural Science Foundation of China 21571034

Figures(6)

Two novel metal-organic coordination compounds, [Co₂(OH)(chdc)_1.5(bibp)]_n (1) and [Ni(chdc)(bib)]_n·2nH₂O (2) (H₂chdc =1, 4-cyclohexanedicarboxylic acid, bibp = 4, 4'-bis(1-imidazolyl)biphenyl, bib=1, 4-bis(1-imidazolyl)benzene), were synthesized and characterized. Compound 1 crystallizes in monoclinic, space group P\begin{document}$ \overline 1 $\end{document} with a = 10.591(3), b = 11.146(3), c = 12.264(3) Å, α = 89.009(6), β = 88.397(4), γ = 87.823(3)°. V = 1446.0(6) Å³, D_c = 1.554 g/cm³, C₃₀H₃₀Co₂N₄O₇, M_r = 676.44 F(000) = 696, μ(MoKα) =1.202 mm^-1, Z = 2, R = 0.0278 and wR = 0.0718. In 1, it contains an interesting tetranuclear Co(II) clusters. The neighboring {Co₄} clusters are linked by chdc^2- ligands to generate a 2D network. The bibp ligands connect adjacent layers to form an open 3D metal–organic framework. Compound 2 crystallizes in monoclinic, space group P2₁/n with a = 8.8110(1), b = 19.369(1), c = 12.7379(4) Å, β = 102.952(5)º, V = 2118.5(2) Å³, D_c = 1.490 g/cm³. C₂₀H₂₄N₄NiO₆, M_r = 475.14 F(000) = 992, μ(MoKα) = 0.961 mm^-1, Z = 4, R = 0.0306 and wR = 0.0738. In 2, each deprotonated chdc^2- ligand links two Ni(II) atoms to generate a 1D chain along the a axis. The adjacent chains are further connected by bib ligands to build up an interesting two-dimensional network. Compound 1 shows antiferromagnetic property.
- coordination polymer,
- magnetic properties,
- cobalt(II) complex,
- nickel(II) complex,
- bis(imidazole) ligand
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