Citation: Cong-Cong JIN, Zi-Bin CHEN, Jian-Wen CHENG. An Unusual (3, 11)-Connected Network Constructed by Tri-nuclear Lanthanide Building Units and Mixed Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(1): 104-109. doi: 10.14102/j.cnki.0254-5861.2011-2381 shu

An Unusual (3, 11)-Connected Network Constructed by Tri-nuclear Lanthanide Building Units and Mixed Ligands

Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: Jian-Wen CHENG, jwcheng@zjnu.cn
Received Date: 29 March 2019
Accepted Date: 4 June 2019

Fund Project: NNSFC 21471130

Figures(3)

Under hydrothermal conditions, a new lanthanide coordination polymer, [Er₃(oba)₄(na)]_n (1, oba = 4, 4'-oxybis(benzoate), na = nicotinic acid) has been synthesized. Compound 1 shows a 3D framework by incorporating tri-nuclear [Er₃(COO)₆] unit and the mixed ligands of oba^2- and na^-. It is interesting that decarboxylation occurred in the ortho position and 2, 3-pyridinedicarboxylic acid was partially transformed into na under hydrothermal conditions. Compound 1 can be reduced into a (3, 11)-connected net and displays weak second-harmonic generation response. Furthermore, the PXRD, TGA and IR spectra were also studied.
- lanthanide,
- coordination polymer,
- mixed ligands,
- second-harmonic generation
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