Citation: Zhen-Tao LI, Li-Wen DING, Yu-Ling WANG. Two Cd(II)-biphenyl-3, 3'-disulfonyl-4, 4'-dicarboxylate-2, 2'-bipyridine Compounds: Structures and Luminescence[J]. Chinese Journal of Structural Chemistry, ;2020, 39(1): 132-139. doi: 10.14102/j.cnki.0254-5861.2011-2380 shu

Two Cd(II)-biphenyl-3, 3'-disulfonyl-4, 4'-dicarboxylate-2, 2'-bipyridine Compounds: Structures and Luminescence

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: Yu-Ling WANG, ylwang@jxnu.edu.cn
Received Date: 29 March 2019
Accepted Date: 27 November 2019

Fund Project: the National Natural Science Foundation of China 21661014the National Natural Science Foundation of China 21861020Natural Science Foundation of Jiangxi Province 20181BAB203001

Figures(10)

Two coordination polymers based on the mixed ligands of biphenyl-3, 3'-disulfonyl-4, 4'-dicarboxylate (BPDSDC^4–) and 2, 2'-bipyridine (2, 2'-bpy), {[Cd(BPDSDC)_0.5(2, 2'-bpy)(H₂O)]·(H₂O)}_n (1) and {[Cd(BPDSDC)_0.5(2, 2'-bpy)₂]·(H₂O)}_n (2) were synthesized. Both compounds crystallize in the monoclinic system, space group P2₁/n. For 1, a = 7.5737(2), b = 17.4284(5), c = 13.5982(5) Å, β = 90.788(3)°, V = 1794.76(10) Å³, Z = 4, C₁₇H₁₅N₂O₇SCd, M_r = 503.77, D_c = 1.864 g/cm³, μ = 1.378 mm^-1, F(000) = 1004, the final R = 0.0299 and wR = 0.0644 for 3137 observed reflections with I > 2σ(I). For 2, a = 13.3097(2), b = 10.66240(10), c = 17.6583(3) Å, β = 91.779(2)°, V = 2504.74(6) Å³, Z = 4, C₂₇H₂₁N₄O₆SCd, M_r = 641.94, D_c = 1.702 g/cm³, μ = 1.008 mm^-1, F(000) = 1292, the final R = 0.0244 and wR = 0.0583 for 4594 observed reflections with I > 2σ(I). The Cd(II) atoms in both compounds are six-coordinated. In 1, the Cd(2, 2'-bpy) units are connected by BPDSDC^4– ligands to generate a one-dimensional (1D) ribbon structure. The 1D ribbons are linked by the hydrogen bonds and π···π interactions to give a three-dimensional (3D) structure. In compound 2, the Cd(2, 2'-bpy)₂ units are linked by the BPDSDC^4– ligands to form a 1D chain. Compounds 1 and 2 show luminescent emissions.
- cadmium coordination polymer,
- biphenyl-3, 3΄-disulfonyl-4, 4΄-dicarboxylate,
- 2, 2΄-bipyridine,
- luminescence,
- crystal structure
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