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Citation: Wei-Sheng LIN, Wen-Tong CHEN. Magnetic, Photoluminescent and Semiconductive Properties of a Novel 4f-5d Bromide Compound (La6Hg5Br26)[4(HgBr2)](2Br)[J]. Chinese Journal of Structural Chemistry, ;2020, 39(1): 154-163. doi: 10.14102/j.cnki.0254-5861.2011-2371 shu

Magnetic, Photoluminescent and Semiconductive Properties of a Novel 4f-5d Bromide Compound (La6Hg5Br26)[4(HgBr2)](2Br)

  • a.

    Department of Ecological and Resources Engineering, Fujian Key Laboratory of Eco-industrial Green Technology, Wuyi University, Wuyishan 354300, China

  • b.

    Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, China

  • c.

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

  • Corresponding author: Wen-Tong CHEN, wtchen_2000@aliyun.com
  • Received Date: 18 March 2019
    Accepted Date: 23 May 2019

    Fund Project: the NNSFC 21361013NSF of Fujian Province 2018J01447Jiangxi Provincial Department of Education's Item of Science and Technology GJJ170637the open foundation of State Key Laboratory of Structural Chemistry 20180008

Figures(8)

  • An unprecedented 4f-5d material (La6Hg5Br26)[4(HgBr2)](2Br) (1) was syn-thesized by hydrothermal reactions and structurally characterized by single-crystal X-ray diffraction method. Complex 1 crystallizes in the Pbam space group of orthorhombic system with a = 13.0980(10), b = 13.6650(9), c = 28.010(2) Å, V = 5013.4(6) Å3, Br36Hg9La6, Mr = 5515.53, Z = 2, Dc = 3.613 g/cm3, μ(MoKα) = 29.457 mm–1 and F(000) = 4598. Compound 1 is characteristic of a two-dimensional (2D) layered structure. The photoluminescent measurements with solid-state samples reveal that compound 1 has a strong emission in the green region of light spectrum. It has remarkable CIE chromaticity coordinates of (0.2499, 0.3589). A wide optical band gap of 3.41 eV is discovered by the solid-state UV/vis diffuse reflectance spectrum. The variable-temperature magnetic susceptibility obeys the Curie-Weiss law (χm = c/(T – θ)) with C = 2.48 K and a negative Weiss constant θ = –169.07 K as revealed by the magnetic measurements, indicating the existence of an antiferromagnetic interaction in compound 1.
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