Citation: Yi-Fen LUO, Lian-Jie ZHAI, Fu-Qiang BI, Huan HUO, Xiang-Zhi LI, Bo-Zhou WANG. A Novel Energetic Ionic Salt: Hydroxylammonium Potassium 3, 3'-Dinitro-5, 5'-bis-1, 2, 4-triazole-1, 1'-diolate Dihydrate[J]. Chinese Journal of Structural Chemistry, ;2020, 39(1): 96-103. doi: 10.14102/j.cnki.0254-5861.2011-2363 shu

A Novel Energetic Ionic Salt: Hydroxylammonium Potassium 3, 3'-Dinitro-5, 5'-bis-1, 2, 4-triazole-1, 1'-diolate Dihydrate

State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

Corresponding author: Bo-Zhou WANG, wbz600@163.com; luoyiluoyiluoyi204@163.com
Received Date: 7 March 2019
Accepted Date: 18 July 2019

Fund Project: the National Natural Science Foundation of China 21805224

Figures(7)

A novel energetic ionic salt, hydroxylammonium potassium 3, 3'-dinitro-5, 5'-bis-1, 2, 4-triazole-1, 1'-diolate dihydrate [(NH₃OH)₂K(DNOBT)_1.5∙2H₂O], was synthesized and structurally characterized by elemental analysis, IR spectra, ¹³C NMR and single-crystal X-ray diffraction. (NH₃OH)₂K(DNOBT)_1.5∙2H₂O crystallizes in triclinic system, space group P\begin{document}$ \overline 1 $\end{document} with a = 7.9212(6), b = 9.1924(7), c = 14.2549(15) Å, α = 103.917(2)°, β = 99.736(2)°, γ = 104.8110(10)°, V = 944.16(14) Å³, Z = 2, D_c = 1.855 g/cm³, F(000) = 538, μ = 0.386 mm^-1, S = 1.070, the final R= 0.0525 and wR(I > 2σ(I))= 0.1593. Thermal decomposition of (NH₃OH)₂K(DNOBT)_1.5∙2H₂O and its intermediate potassium 1'-hydroxy-3, 3'-dinitro-5, 5'-bis-1, 2, 4-triazole-1-olate monohydrate [K(HDNOBT)∙H₂O] was studied by using DSC and TG-DTG. It was found that (NH₃OH)₂K(DNOBT)_1.5∙2H₂O, which has primarily one exothermic decomposition process at 248.2 ℃, has better thermal stability than K(HDNOBT)∙H₂O which is decomposed at 210.9 ℃.
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