Citation: Jin-Fa YU, Min-Jie MAO, Hui-Ping LI, Xian-Bo ZHOU, Dan-Dan ZHANG, Jian-Xin CHEN, Zhi-Chun ZHANG. Synthesis, Characterization and Catalytic Activity of SalenCo(III)Cl in Alternating Copolymerization of CO₂ and Propylene Oxide[J]. Chinese Journal of Structural Chemistry, ;2020, 39(1): 86-95. doi: 10.14102/j.cnki.0254-5861.2011-2352 shu

Synthesis, Characterization and Catalytic Activity of SalenCo(III)Cl in Alternating Copolymerization of CO₂ and Propylene Oxide

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Jian-Xin CHEN, jxchen_1964@163.com
Received Date: 4 March 2019
Accepted Date: 11 April 2019

Fund Project: the Natural Science Foundation of Fujian Province 2010J01026the Ministry of Education of China 208066the Education Department of Fujian Province JA07029the State Key Laboratory of Structural Chemistry 20130013

Figures(12)

The title complex SalenCo(III)Cl (Salen = 6, 6'-((1E, 1'E)-(cyclohexane-1, 2-diylbis(azaneylylidene))bis(methaneylylidene))bis(2, 4-di-tert-butylphenol)) was synthesized and characterized by elemental analysis, IR spectroscopy, ¹H NMR and UV-Vis. The complex can be used as catalyst for the propylene oxide (PO)/CO₂ copolymerization in different conditions of reaction time, reaction temperature, carbon dioxide pressure and monomer concentration, and the optimum conditions for copolymerization were obtained.
- cobalt(III) complex,
- salen,
- ploy(propylene carbonate),
- catalytic activity
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Characterization and Catalytic Activity of SalenCo(III)Cl in Alternating Copolymerization of CO2 and Propylene Oxide

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Characterization and Catalytic Activity of SalenCo(III)Cl in Alternating Copolymerization of CO₂ and Propylene Oxide