Citation: SHEN Yao-Guo, ZHAO San-Gen, LUO Jun-Hua. K₂SbB₃O₈: A Novel Boroantimonate with Isolated [B₃O₈]^7- Groups[J]. Chinese Journal of Structural Chemistry, ;2016, 35(8): 1269-1276. doi: 10.14102/j.cnki.0254-5861.2011-1143 shu

K₂SbB₃O₈: A Novel Boroantimonate with Isolated [B₃O₈]^7- Groups

1.
a Department of Physics and Electronic Information Engineering, Minjiang University, Fuzhou 350108, China;
2.
b Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: LUO Jun-Hua,
Received Date: 20 January 2016
Available Online: 14 April 2016
Fund Project: NSF of Fujian Province (2015J01219, 2015J05040) (CMZX-2015-003)

A new boroantimonate K₂SbB₃O₈ has been synthesized by high-temperature solidstate reactions, and its crystals have been obtained by the flux method. The crystal structure has been determined from single-crystal X-ray diffraction analysis. The compound crystallizes in the monoclinic space group P2₁/c with a=5.8890(2), b=11.0512(4), c=10.8951(4)Å, β=103.200(4)°, V=690.32(4)Å³, Z=4, F(000)=672, ρ_c=3.467 g/cm³, M_r=360.38 and μ=5.215 mm^-1. Its structure feature is a three-dimensional framework composed of SbO₆ octahedra and isolated [B₃O₈]^7- groups with K⁺ cations residing in the one-dimensional tunnels along the a-axis. Interestingly, the isolated [B₃O₈]^7- groups are distinct from the known [B₃O₈]^7- groups, which always connect to each other. The UV-vis-NIR absorption, thermal stability and infrared spectrum are also discussed in this paper.
- borate,
- crystal structure,
- isolated group,
- infrared spectrum
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