Citation: PANG Tao, WANG Hui, WU Xue, WU Lin, ZHAO Zhi-Yong, WU Gen-Hua. Synthesis, Crystal Structure and Fluorescence of a Bicyclic Product Containing Chromene and Propargylamine Skeleton[J]. Chinese Journal of Structural Chemistry, ;2016, 35(8): 1277-1282. doi: 10.14102/j.cnki.0254-5861.2011-1069 shu

Synthesis, Crystal Structure and Fluorescence of a Bicyclic Product Containing Chromene and Propargylamine Skeleton

PANG Tao ^a ,
WANG Hui ^a ,
WU Xue ^a ,
WU Lin ^a ,
ZHAO Zhi-Yong ^b ,
WU Gen-Hua ^a

1.
a Anhui Provincial Laboratory of Optoelectronic and Magnetism Functional Materials, Anqing Normal University, Anqing 246011, China;
2.
b College of Chemical Engineering and Technology, Wuhan University of Science and Technology, Hubei 430081, China

Received Date: 27 November 2015
Available Online: 20 January 2016
Fund Project: This work was supported by the Natural Science Foundation of Anhui Province Education Department (No. KJ2014A141) (No. KJ2014A141)the National Natural Science Foundation of China (No. 21171008) (No. 21171008)

The bicyclic product containing a chromene skeleton and a propargylamine skeleton (C₂₂H₂₂N₂O₂) was synthesized from the double sites of terminal alkyne, piperazine derivative and formaldehyde via one-pot procedure. Its structure was characterized by ¹H NMR, ¹³C NMR, IR and H RMS, and further confirmed by single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group P2₁/n with a=12.6571(14), b=11.3249(12), c=12.6571(14)Å, β=105.22°, V=1750.6(3)Å³, Z=4, R=0.0568 and wR=0.1444. The fluorescence of the product was discussed.
- crystallography,
- fluorescence,
- bicyclization,
- chromene skeleton,
- propargylamine skeleton
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