Citation: YU You-Yi, ZHANG Heng-Qiang. Reduced Graphene Oxide Coupled Magnetic CuFe₂O₄-TiO₂ Nanoparticles with Enhanced Photocatalytic Activity for Methylene Blue Degradation[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 472-480. doi: 10.14102/j.cnki.0254-5861.2011-1041 shu

Reduced Graphene Oxide Coupled Magnetic CuFe₂O₄-TiO₂ Nanoparticles with Enhanced Photocatalytic Activity for Methylene Blue Degradation

YU You-Yi ^a,, ,
ZHANG Heng-Qiang ^b

1.
a School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, China;
2.
b Department of Chemistry, Hebei Normal University for Nationalities, Chengde, Hebei 067000, China

Corresponding author: YU You-Yi,
Received Date: 4 November 2015
Available Online: 14 December 2015
Fund Project: Supported by the National Natural Science Function of China (No. 21303058) (No. 21303058)

CuFe₂O₄-TiO₂/graphene nanocomposites have been prepared via a one-step hy-drothermal method, and the as-prepared CuFe₂O₄-TiO₂/graphene was characterized by X-ray powder diffraction, Raman spectroscopy, scanning electron microscopy and transmission electron microscopy. The transmission electron microscopy demonstrated that CuFe₂O₄-TiO₂ nanoparticles were successfully dispersed on the graphene sheets. Photocatalytic activity of nanocomposites was evaluated in terms of degradation of methylene blue (MB) dye solution under visible light radiation. Results showed that the photocatalytic efficiency of CuFe₂O₄-TiO₂/graphene nanocomposites was higher than its individual pure oxides (CuFe₂O₄ or TiO₂) and TiO₂/graphene. The enhancing photocatalytic activity performance of the CuFe₂O₄-TiO₂/graphene nanocomposites may attributed to the mutual effect between the CuFe₂O₄, TiO₂ nanoparticles and the graphene sheets. Moreover, CuFe₂O₄ nanoparticles have excellent magnetic property, which makes the CuFe₂O₄-TiO₂/graphene heteroarchitecture magnetically recyclable in a suspension system.
- photocatalysts,
- magnetic,
- CuFe₂O₄-TiO₂,
- graphene
1. [1]
  (1) Geim, A. K.; Novoselov, K. S. The rise of graphene. Nat. Mater. 2007, 6, 183-191.
2. [2]
  (2) Bonaccorso, F.; Sun, Z.; Hasan, T.; Ferrari, A. C. Graphene photonics and optoelectronics. Nat. Photonics. 2010, 4, 611-622.
3. [3]
  (3) Kamat, P. V. Graphene-based nanoassemblies for energy conversion. J. Phys. Chem. Lett. 2010, 2, 242-251.
4. [4]
  (4) Subramanian, V.; Wolf, E.; Kamat, P. V. Semiconductor-metal composite nanostructures. To what extent do metal nanoparticles improve the photocatalytic activity of TiO₂ films. J. Phys. Chem. B. 2001, 105, 11439-11446.
5. [5]
  (5) Wang, N.; Chen, Z.; Zhu, L.; Jiang, X.; Lv, B.; Tang, H. Synergistic effects of cupric and fluoride ions on photocatalytic degradation of phenol. J. Photochem. Photobiol. A: Chem. 2007, 191, 193-200.
6. [6]
  (6) Wang, L.; Wang, N.; Zhu, L.; Yu, H.; Tang, H. Photocatalytic reduction of Cr (VI) over different TiO₂ photocatalysts and the effects of dissolved organic species. J. Hazard. Mater. 2008, 1, 93-99.
7. [7]
  (7) Shen, X.; Zhu, L.; Li, J.; Tang, H. Synthesis of molecular imprinted polymer coated photocatalysts with high selectivity. Chem. Commun. 2007, 11, 1163-1165.
8. [8]
  (8) Tada, H.; Konishi, Y.; Kokubu, A. Patterned TiO₂/SnO₂ bilayer type photocatalyst.3. Preferential deposition of Pt particles on the SnO₂ underlayer and its effect on photocatalytic activity. Langmuir. 2004, 20, 3816-3819.
9. [9]
  (9) Li, J.; Zhu, L.; Wu, Y.; Harima, Y.; Zhang, A.; Tang, H. Hybrid composites of conductive polyaniline and nanocrystalline titanium oxide prepared via self-assembling and graft polymerization. Polymer. 2006, 47, 7361-7367.
10. [10]
  (10) Rajeshwara, K.; Osugib, M. E.; Chanmaneec, W.; Chenthamarakshana, C. R.; Zanonib, M. V.; Kajitvichyanukuld, B. P.; Krishnan-Ayera, R. Heterogeneous photocatalytic treatment of organic dyes in air and aqueous media. J. Photochem. Photobiol. C 2008, 9, 171-192.
11. [11]
  (11) Wang. Y. F.; Li, L. P.; Huang, X. S.; Li, G. S. A new Ti³⁺-assisted synthesis of Pd-supported TiO₂ nanomaterial with enhanced photocatalytic activity for hydrogen generation and methyl orange degradation. Chin. J. Struct. Chem. 2015, 8, 1203-1216.
12. [12]
  (12) Xu, Z.; Quintanilla, M.; Vetrone, F.; Govorov, A. O.; Chaker, M.; Ma, D. Plasmon and upconversion enhanced broadband photocatalytic activity in core @ shell microspheres based on lanthanide-doped NaYF₄, TiO₂, and Au. Adv. Funct. Mater. 2015, 25, 2950-2960.
13. [13]
  (13) Tien, H. N.; Luan, V. H.; Hoa, L. T.; Khoa, N. T.; Hahn, S. H.; Chung, J. S.; Shin, E.W.; Hur, S. H. One-pot synthesis of a reduced graphene oxide-zinc oxide sphere composite and its use as a visible light photocatalyst. Chem. Eng. J. 2013, 229, 126-133.
14. [14]
  (14) Jiang, J. Z.; Goya, G. F.; Rechenberg, H. R. Magnetic properties of nanostructured CuFe₂O₄.J. Phys. Condens. Matter. 1999, 11, 4063-4078.
15. [15]
  (15) Zhang, G. S.; Qu, J. H.; Liu, H. J.; Cooper, A. T.; Wu, R. C. CuFe₂O₄/activated carbon composite: a novel magnetic adsorbent for the removal of acid orange II and catalytic regeneration. Chemosphere 2007, 68, 1058-1066.
16. [16]
  (16) Bomio, M.; Lavela, P.; Tirado, J. L. Electrochemical evaluation of CuFe₂O₄ samples obtained by sol-gel methods used as anodes in lithium batteries. J. Solid State Electrochem. 2008, 12, 729-737.
17. [17]
  (17) Sun, Z. P.; Liu, L.; Jia, D. Z.; Pan, W. Y. Simple synthesis of CuFe₂O₄ nanoparticles as gas-sensing materials. Sensor. Actuat. B-Chem. 2007, 125, 144-148.
18. [18]
  (18) Kameokaa, S.; Tanabe, T.; Tsai, A. P. Spinel CuFe₂O₄: a precursor for copper catalyst with high thermal stability and activity. Catal. Lett. 2005, 100, 89-93.
19. [19]
  (19) Saadi, S.; Bouguelia, A.; Trari, M. Photoassisted hydrogen evolution over spinel CuM₂O₄ (M = Al, Cr, Mn, Fe and Co). Renew. Energ. 2006, 31, 2245-2256.
20. [20]
  (20) Xu, Y.; Bai, H.; Lu, G. W.; Li, C.; Shi, G. Q. Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets. J. Am. Chem. Soc. 2008, 130, 5856-5857.
21. [21]
  (21) Yang, H.; Yan, J.; Lu, Z.; Cheng, X.; Tang, Y. Photocatalytic activity evaluation of tetragonal CuFe₂O₄nanoparticles for the H₂ evolution under visible light irradiation. J. Alloy. Compd. 2009, 476, 715-719.
22. [22]
  (22) Wang, J.; Zhu, H.; Hurren, C.; Zhao, J.; Pakdel, E.; Li, Z. Degradation of organic dyes by P25-reduced graphene oxide: influence of inorganic salts and surfactants. J. Environ. Chem. Engin. 2015, 3, 1437-1443.
23. [23]
  (23) Stankovich, S.; Dikin, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y.; Wu, Y.; Nguyen, S. T.; Ruoff, R. S. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 2007, 45, 1558-1565.
24. [24]
  (24) Lambert, T. N; Chavez, C. A.; Hernandez-Sanchez, B.; Lu, P.; Bell, N. S. Synthesis and characterization of titania-graphene nanocomposites. J. Phys. Chem. C 2009, 113, 19812-19823.
25. [25]
  (25) Vasu, K. S.; Chakraborty, B.; Sampath, S.; Sood, A. K. Probing top-gated field effect transistor of reduced graphene oxide monolayer made by dielectrophoresis. Solid State Commun. 2010, 150, 1295-1298.
26. [26]
  (26) Ray, S. C.; Saha, A.; Basiruddin, S. K.; Roy, S. S.; Jana, N. R. Polyacrylate-coated graphene-oxide and graphene solution via chemical route for various biological application. Diamond Relat. Mater. 2011, 20, 449-453.
27. [27]
  (27) Ferrari, A. C.; Meyer, J. C.; Casiraghi, V. C.; Lazzeri, M.; Mauri, F.; Piscanec, S.; Jiang, D.; Novoselov, K. S.; Roth, S.; Geim, A. K. Raman spectrum of graphene and graphene layers. Phys. Rev. Lett. 2006, 97, 187401-187405.
28. [28]
  (28) Hernandez, Y.; Nicolosi, V.; Ltya, M. F.; Blighe, M.; Sun, Z.; De, S.; Mcgovern, I. T.; Holland, B.; Byrne, M.; Gun'ko, Y. K.; Boland, J. J.; Niraj, P.; Duesberg, G.; Krishnamurthy, S.; Goodhue, R.; Hutchison, J.; Scardaci, V.; Ferrari, A. C.; Coleman, J. N. High-yield production of graphene by liquid-phase exfoliation of graphite. Nat. Nanotechnol. 2008, 3, 563-568.
29. [29]
  (29) Li, X.; Zhang, G.; Bai, X.; Sun, X.; Wang, X.; Wang, E.; Dai, H. Highly conducting graphene sheets and Langmuir-Blodgett films. Nat. Nanotechnol. 2008, 3, 538-542.
30. [30]
  (30) Meyer, J. C.; Geim, A. K.; Katsnelson, M. I.; Novoselov, K. S.; Booth, T. J.; Roth, S. The structure of suspended graphene sheets. Nature 2007, 446, 60-63.
31. [31]
  (31) Wang, X.; Zhi, L. J.; Mullen, K. Conductive graphene electrodes for dye-sensitized solar cells. Nano. Lett. 2008, 8, 323-327.
32. [32]
  (32) Zhang, Y. P.; Pan, C. X. TiO₂/graphene composite from thermal reaction of graphene oxide and its photocatalytic activity in visible light. J. Mater. Sci. 2011, 46, 2622-2626.
1. [1]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
2. [2]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
3. [3]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
4. [4]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
5. [5]
  Jing Wang , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Single-layer crystalline triazine-based organic framework photocatalysts with different linking groups for H2O2 production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100202-100202. doi: 10.1016/j.cjsc.2023.100202
6. [6]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
7. [7]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
8. [8]
  Xiaoming Fu , Haibo Huang , Guogang Tang , Jingmin Zhang , Junyue Sheng , Hua Tang . Recent advances in g-C3N4-based direct Z-scheme photocatalysts for environmental and energy applications. Chinese Journal of Structural Chemistry, 2024, 43(2): 100214-100214. doi: 10.1016/j.cjsc.2024.100214
9. [9]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
10. [10]
  Jie Zhou , Chuanxiang Zhang , Changchun Hu , Shuo Li , Yuan Liu , Zhu Chen , Song Li , Hui Chen , Rokayya Sami , Yan Deng . Electrochemical aptasensor based on black phosphorus-porous graphene nanocomposites for high-performance detection of Hg²⁺. Chinese Chemical Letters, 2024, 35(11): 109561-. doi: 10.1016/j.cclet.2024.109561
11. [11]
  Xin Wang , Changzhao Chen , Qishen Wang , Kai Dai . Graphene quantum dot modified Bi2MoO6 nanoflower for efficient degradation of BPA under visible light. Chinese Journal of Structural Chemistry, 2024, 43(12): 100473-100473. doi: 10.1016/j.cjsc.2024.100473
12. [12]
  Sushu Zhang , Yang Yang , Jingyu Wang . Pyridinic nitrogen-substituted graphene membranes for exceptional CO2 capture. Chinese Journal of Structural Chemistry, 2025, 44(2): 100440-100440. doi: 10.1016/j.cjsc.2024.100440
13. [13]
  Sanmei Wang , Yong Zhou , Hengxin Fang , Chunyang Nie , Chang Q Sun , Biao Wang . Constant-potential simulation of electrocatalytic N₂ reduction over atomic metal-N-graphene catalysts. Chinese Chemical Letters, 2025, 36(3): 110476-. doi: 10.1016/j.cclet.2024.110476
14. [14]
  Sanmei Wang , Dengxin Yan , Wenhua Zhang , Liangbing Wang . Graphene-supported isolated platinum atoms and platinum dimers for CO₂ hydrogenation: Catalytic activity and selectivity variations. Chinese Chemical Letters, 2025, 36(4): 110611-. doi: 10.1016/j.cclet.2024.110611
15. [15]
  Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO₂ nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
16. [16]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833
17. [17]
  Jun Dong , Senyuan Tan , Sunbin Yang , Yalong Jiang , Ruxing Wang , Jian Ao , Zilun Chen , Chaohai Zhang , Qinyou An , Xiaoxing Zhang . Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage. Chinese Chemical Letters, 2025, 36(3): 110010-. doi: 10.1016/j.cclet.2024.110010
18. [18]
  Caili Yang , Tao Long , Ruotong Li , Chunyang Wu , Yuan-Li Ding . Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors. Chinese Chemical Letters, 2025, 36(2): 109675-. doi: 10.1016/j.cclet.2024.109675
19. [19]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
20. [20]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(859)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Reduced Graphene Oxide Coupled Magnetic CuFe2O4-TiO2 Nanoparticles with Enhanced Photocatalytic Activity for Methylene Blue Degradation

Metrics

通讯作者: 陈斌, bchen63@163.com

Reduced Graphene Oxide Coupled Magnetic CuFe₂O₄-TiO₂ Nanoparticles with Enhanced Photocatalytic Activity for Methylene Blue Degradation