Citation: ZHANG Xin, SUN Ming-Ling, QIN Ye-Yan, YAO Yuan-Gen. Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a Cd(II) Compound with (4,6)-Connected Topology[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 914-920. doi: 10.14102/j.cnki.0254-5861.2011-1001 shu

Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a Cd(II) Compound with (4,6)-Connected Topology

a.
a. Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
b.
b. University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: YAO Yuan-Gen,
Received Date: 9 September 2015
Available Online: 28 October 2015
Fund Project: Supported by the 973 Program of China (2011CBA00505) (2011CBA00505) the "Strategic Priority Research Program" of the Chinese Academy of Sciences (XDA07070200, XDA09030102) (XDA07070200, XDA09030102)

A new Cd(II) coordination polymer, namely {Cd₂(L)(biimpy)(H₂O)}_n (1, H₄L = 3-(3',5'-dicarboxylphenoxy)phthalic acid, biimpy = 2,6-bis(1-imdazoly)pyridine), has been success- fully synthesized via the hydrothermal reactions of Cd(II) ions, H₄L and biimpy. The crystal structure is of triclinic, space group P with a = 7.7874(5), b = 9.9716(5), c = 18.5278(6) Å, α = 91.327(4), β = 96.689(4), γ = 111.896(5)°, V = 1322.39(12) Å³, C₂₇H₁₇Cd₂N₅O₁₀, M_r = 796.26, Z = 2, D_c = 2.000 g/cm³, F(000) = 780, μ = 1.679 mm^-1, R= 0.0345 and wR= 0.0767 for 3890 observed reflections (I > 2s(I)). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional (3D) framework based on two different dinuclear [Cd₂(COO)₂] building subunits, and topological analysis shows that it can be simplified into a binodal (4,6)-connected topological network with the point symbol of {3.4².5².6}{3².4².5².6⁴.7⁴.8}. Moreover, the thermal stability and luminescent property of compound 1 were also studied.
- Cd(II) compound,
- hydrothermal reaction,
- 3D framework,
- luminescence
1. [1]
  (1) Zhang, X. J.; Wang, W. J.; Hu, Z. J.; Wang, G. N.; Uvdal, K. S. Coordination polymers for energy transfer: preparations, properties, sensing applications, and perspectives. Coord. Chem. Rev. 2015, 284, 206–235.
2. [2]
  (2) Chen, W. T. Synthesis, and characterization of a novel cadmium-biimidazole compound with a 1-D chain-like motif. Synth. React. Inorg. M 2015, 45, 315–318.
3. [3]
  (3) Yun, R. R.; Lu, Z. Y.; Pan, Y.; You, X. Z.; Bai, J. F. Formation of a metal-organic framework with high surface area and gas uptake by breaking edges off truncated cuboctahedral cages. Angew. Chem. Int. Ed. 2013, 52, 11282-11285.
4. [4]
  (4) Yao, Z. L.; Chen, W. T.; Hu, R. H. Photoluminescence and theoretical study of [∞(Cd₂Cl₆)][2(CdCl₄]][3(N,N'-dimethyl)-4,4'-bipyridinium)]. Indian J. Chem. Sec. A 2015, 54, 489–493.
5. [5]
  (5) Feng, X.; Wen, Y. H.; Lan, Y. Z.; Feng, Y. L.; Pan, C. Y.; Yao, Y. G., Multifunctional zinc(II) urocanate with rare fivefold interpenetrating diamondoid network. Inorg. Chem. Commun. 2009, 89–91.
6. [6]
  (6) Luo, F.; Wang, M. S.; Luo, M. B.; Sun, G. M.; Song, Y. M.; Li, P. X.; Guo, G. C. Functionalizing the pore wall of chiral porous metal-organic frameworks by distinct -H, -OH, -NH₂, -NO₂, -COOH shutters showing selective adsorption for CO₂, tunable photoluminescence and direct white emission. Chem. Commun. 2012, 48, 5989–5991.
7. [7]
  (7) Chen, Y. F.; Ma, Y. C.; Chen, S. M. A chiral tetrahedral guests for catalysis and photoluminescence. Cryst. Growth & Des. 2013, 13, 4154–4157.
8. [8]
  (8) Mulfort, K. L.; Farha, O. K.; Malliakas, C. D.; Kanatzidis, M. G.; Hupp, J. An interpenetrated framework material with hysteretic CO₂ uptake. Chem. Eur. J. 2010, 16, 276–281.
9. [9]
  (9) Zhang, X.; Huang, Y. Y.; Lin, Q. P.; Zhang, J.; Yao, Y. G. Using alkaline-earth metal ions to tune structural variations of coordination polymers. Dalton Trans. 2013, 42, 2294–2301.
10. [10]
  (10) Zhang, X.; Huang, Y. Y.; Zhang, M. J.; Zhang, J.; Yao, Y. G. A series of Ca(II) or Ba(II) inorganic-organic hybrid frameworks based on aromatic polycarboxylate ligands with the inorganic M-O-M (M = Ca, Ba) connectivity from 1D to 3D. Cryst. Growth Des. 2012, 12, 3231–3238.
11. [11]
  (11) Guo, F.; Wang, F.; Yang, H.; Zhang, X.; Zhang, J. Tuning structural topologies of three photoluminescent metal-organic frameworks via isomeric biphenyl-dicarboxylates. Inorg. Chem. 2012, 51, 9677–9682.
12. [12]
  (12) Zhang, X.; Huang, Y. Y.; Cheng, J. K.; Yao, Y. G.; Zhang, J.; Wang, F. Alkaline-earth metal ion doped Zn(II)-terephthalates. CrystEngComm. 2012, 14, 4843–4849.
13. [13]
  (13) Yang, J. X.; Zhang, X.; Cheng, J. K.; Zhang, J.; Yao, Y. G. pH influence on the structural variations of 4,4'-oxydiphthalate coordination polymers. Cryst. Growth Des. 2012, 12, 333–345.
14. [14]
  (14) Guo, F.; Zhu, B. Y.; Xu, G. L.; Zhang, M. M.; Zhang, X. L.; Zhang, J. Tuning structural topologies of five photoluminescent Cd(II) coordination polymers through modifying the substitute group of organic ligand. J. Solid State Chem. 2013, 199, 42–48.
15. [15]
  (15) Bu, X. Z.; Wei, Z. W.; Ren, S. F. Synthesis, structures and magnetic properties of two isomeric coordination polymers constructed from pamoic acid and 1,2-di(4-pyridyl)ethane. J. Coord. Chem. 2015, 68, 471–478.
16. [16]
  (16) Zhang, J.; Chew, E.; Chen, S. M.; Jimmy, T. H. P.; Bu, X. H. Three-dimensional homochiral transition-metal camphorate architectures directed by a flexible auxiliary ligand. Inorg. Chem. 2008, 47, 3495–3497.
17. [17]
  (17) Zhang, J.; Chen, Y. B.; Li, Z. J.; Cheng, J. K.; Kang, Y.; Yao, Y. G. A polar luminescent Zn polymer containing an unusual noninterpenetrated utp net. Inorg. Chem. 2006, 45, 3161–3163.
18. [18]
  (18) Guo, J. S.; Xu, G.; Wang, S. H.; Wang, M. S.; Zhang, M. J.; Guo, G. C.; Huang, J. S. Blue emission of a 2D non-interpenetrated zinc coordination polymer constructed through saturated fatty acid ligand. Inorg. Chem. Comm. 2014, 45, 108–111.
19. [19]
  (19) Yang, D. L.; Zhang, X.; Yang, J. X.; Yao, Y. G.; Zhang, J. Alkali/alkaline earth metal and solvents-regulated construction of novel heterometallic coordination polymers based on a semirigid ligand and tetranuclear metal clusters. Inorg. Chim. Acta 2014, 423, 62–71.
20. [20]
  (20) Li, X. H.; Zhou, P. P.; Dong, Y. L.; Liu, H. M. Structural diversity of a series of 2D Zn(II) coordination polymers tuned by different dicarboxylic acids ligands. J. Inorg. Organomet. Polym. 2015, 25, 650–656.
21. [21]
  (21) Sheldrick, G. M. SADABS, Program for Area Detector Adsorption Correction. Institute for Inorganic Chemistry, University of Göttingen: Göttingen, Germany 1996.
22. [22]
  (22) Sheldrick, G. M. SHELXS-97, Program for Solution of Crystal Structure. University of Göttingen: Göttingen, Germany 1997.
23. [23]
  (23) Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structure. University of Göttingen: Göttingen, Germany 1997.
24. [24]
  (24) Qiao, L. Y.; Zhang, X.; Yang, J. X.; Li, Z. J.; Yao, Y. G. Synthesis, structure and topological analysis of a new zinc(II) complex [Zn₂(bptc)(bpe)(H₂O)]_n. Chin. J. Struct. Chem. 2011, 30, 1006–1010.
25. [25]
  (25) Ma, D. X.; Li, B. Y.; Zhou, X. J.; Zhou, Q.; Liu, K.; Zeng, G.; Li, G. H.; Shi, Z.; Feng, S. H. A dual functional MOF as a luminescent sensor for quantitatively detecting the concentration of nitrobenzene and temperature. Chem. Comm. 2013, 49, 8964–8966.
26. [26]
  (26) Li, L. N.; Zhang, S. Q.; Xu, L. J.; Han, L.; Chen, Z. N.; Luo, J. H. An intensely luminescent metal-organic framework based on a highly light-harvesting dyclo-metalated iridium(III) unit showing effective detection of explosives. Inorg. Chem. 2013, 52, 12323–12325.
27. [27]
  (27) Yang, D. L.; Zhang, X.; Zhang, J.; Yao, Y. G. Structure versatility of coordination polymers constructed from a semirigid ligand and polynuclear metal clusters. CrystEngComm. 2014, 16, 8047–8057.
28. [28]
  (28) Gong, Y. Q.; Mi, T. Q.; Jiang, F. L. Synthesis, crystal structure and photoluminescence of a Zn(II) coordination polymer derived from 1,1'-biphenyl-2,2',6,6'-tetracarboxylic acid. Chin. J. Struct. Chem. 2015, 34, 1087–1091.
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