Citation: ZHAO Qiang, SHEN Zhi, LIU Wen-Min, SONG Hui-Zhen, HE Ze-Ying. Crystal Structure and Spectroscopic Analysis of Polypyridyl Quinoxaline with Ce(III) and Nd(III)[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 939-945. doi: 10.14102/j.cnki.0254-5861.2011-0988 shu

Crystal Structure and Spectroscopic Analysis of Polypyridyl Quinoxaline with Ce(III) and Nd(III)

1.
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061, China

Received Date: 28 September 2015
Available Online: 8 January 2016
Fund Project: This work was supported by the NNSFC (21301100) (21301100) the Education Department Fund of Henan (13A150819) (13A150819)Special fund of Nanyang Normal University (ZX2013029) (ZX2013029)

Two high coordination crystals were obtained by the interaction of Ce³⁺ and Nd³⁺ with polypyridyl quinoxaline ligand 2,3,6,7,10,11-hexakis(2-pyridyl)dipyrazino[2,3-f:20,30-h]qui- noxaline (HPDQ), and they were characterized. Complex 1 exhibits a 0 dimensional three-nuclear structure, with the three Ce(III) atoms being ten-, eleven- and twelve-coordinated. Complex 2 is a 0 dimensional dual-core structure and the Nd(III) atom is ten-coordinated. Complex 1 is of mono- clinic system, space group P2/c with a = 16.850(3), b = 16.617(3), c = 24.017(5) Å, β = 100.94(3)^o, V = 6602(2) Å³, Z = 4, S = 1.062, F(000) = 3372, R= 0.0504 and wR= 0.1463 (I> 2σ(I)). Complex 2 adopts a monoclinic system, space group C2/c with a = 25.795(5), b = 20.166(4), c = 13.059(3) Å, β = 112.29(3)^o, V = 6286(2) Å³, Z = 4, S = 1.004, F(000) = 2664, R= 0.0663 and wR= 0.1821 (I > 2σ(I)). Furthermore, the behaviors of HPDQ with Ce³⁺ and Nd³⁺in the solution are also investigated. After the Ce³⁺ is added, the ultraviolet absorption of the solution is enhanced with a red shift compared with that of the HPDQ ligand. While after adding Nd³⁺, the ultraviolet absorption of the solution is weakened, and it has a red shift which is the same as Ce³⁺. However, after the respective addition of metal ions, the emission of all solutions is quenched and has a red shift compared with that of the HPDQ ligand.
- polypyridyl quinoxaline,
- cerium(III),
- neodymium(III),
- fluorescence spectrum
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