Citation: CHI Yang, GUO Sheng-Ping. Syntheses and Crystal Structures of Two Al_xRE₃(Si_1-yAl_y)S₇ (RE = Sm and Gd) Compounds[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 341-347. doi: 10.14102/j.cnki.0254-5861.2011-0978 shu

Syntheses and Crystal Structures of Two Al_xRE₃(Si_1-yAl_y)S₇ (RE = Sm and Gd) Compounds

CHI Yang ,
GUO Sheng-Ping ^,

1.
College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

Corresponding author: GUO Sheng-Ping,
Received Date: 16 September 2015
Available Online: 19 November 2015
Fund Project: This research was supported by the Higher Education Science Foundation of Jiangsu Province (No. 15KJB150031) (No. 15KJB150031) State Key Laboratory of Structural Chemistry (No. 20150009) (No. 20150009)

Two new quaternary rare-earth chalcogenides, Al_0.42Sm₃(Si_0.74Al_0.26)S₇ (1) and Al_0.38Gd₃(Si_0.86Al_0.14)S₇ (2), have been synthesized by a facile solid-state route with boron as the reducing reagent. They crystallize in the noncentrosymmetric hexagonal space group P6₃, belonging to the Ce₆Al_3.33S₁₄ structure-type. Their 3-D structures feature 3-D frameworks constructed by RES₈ bicapped trigonal prisms, and Al and Si occupy the octahedral and tetrahedral voids, respectively. Al(2) and Si(1) co-occupying the 2b site and Al(1) partially occupying the 2a site have to be considered for the stability of the structures and charge balances. The Ce₆Al_3.33S₁₄ structure-type compounds with their rich compositions and traits are discussed. The diffuse reflectance spectrum measurement of 2 indicates that it has an energy gap of 2.13 eV.
- rare-earth chalcogenides,
- solid-state reaction,
- crystal structure,
- energy gap
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Syntheses and Crystal Structures of Two AlxRE3(Si1-yAly)S7 (RE = Sm and Gd) Compounds

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Syntheses and Crystal Structures of Two Al_xRE₃(Si_1-yAl_y)S₇ (RE = Sm and Gd) Compounds