Citation: WANG Xiao-Ning, WANG Yu-Fang, GENG Jun-Lei, LI Fei-Fei. Synthesis, Structure and Magnetic Property of a New Three-dimensional Copper(II) Coordination Polymer Constructed from 5-Tert-butyl Isophthalic Acid and N-donor Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 953-958. doi: 10.14102/j.cnki.0254-5861.2011-0973 shu

Synthesis, Structure and Magnetic Property of a New Three-dimensional Copper(II) Coordination Polymer Constructed from 5-Tert-butyl Isophthalic Acid and N-donor Ligand

a.
a. Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo 454000, China;
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b. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Received Date: 10 September 2015
Available Online: 6 December 2015
Fund Project:

A new 3D copper(II) coordination polymer, {[Cu₂(tbip)₂(1,3,5-tib)]·2H₂O}_n (1, H₂tbip = 5-tert-butyl isophthalic acid, 1,3,5-tib = 1,3,5-tris(1-imidazolyl)benzene), has been synthe- sized by hydrothermal reaction of Cu(OAc)₂·4H₂O, H₂tbip and 1,3,5-tib. It has been structurally characterized by element analysis, IR and magnetic measurement. X-ray single-crystal analysis was carried out for 1, which crystallizes in the triclinic system, space group P with a = 7.822(3), b = 15.854(6), c = 17.553(6) Å, a = 113.033(4), β = 90.694(4), g = 101.006(4)°, V = 1957.3(12) Å³, Z = 1, D_c = 1.493 g/cm³, M_r = 1759.70, F(000) = 908, R = 0.0721 and wR = 0.1978 with I > 2s(I). The single-crystal X-ray diffraction studies reveal that compound 1 exhibits 2D [Cu(tbip)] layers which are further pillared by 1,3,5-tib ancillary ligand with terminal tridentate coordination mode to generate the final 3D structure. Magnetic susceptibility data for 1 have been measured in the range of 2~300 K. There are antiferromagnetic interactions between copper ions of the compound.
- copper(II),
- coordination polymer,
- antiferromagnetic interaction
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