Citation:
ZHANG You-Juan, YANG Jin-Hui, WANG Jun-Jie, CHEN Jing. Synthesis, Crystal Structure and Magnetic Properties of a Cobalt(II) Complex with Quinoxaline-substituted Nitronyl Nitroxide Radicals[J]. Chinese Journal of Structural Chemistry,
;2016, 35(6): 959-964.
doi:
10.14102/j.cnki.0254-5861.2011-0970
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A new complex with the formula [Co(acac)2(NITQ)2]·2CH2Cl2 1 (acac = acety- lacetone, NITQ = 2-(2´-quinoxalinyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide), was synthe- sized and elucidated structurally as well as magnetically in detail. The crystal belongs to the mono- clinic system, space group P21/c with a = 9.6896(1), b = 20.539(4), c = 12.147(2) Å, β = 93.84(3)°, Mr = 997.65, V = 2412.1(8) Å3, Z = 2, Dc = 1.374 g/cm3, F(000) = 1038, m = 0.635 mm-1, the final R = 0.0539 and wR = 0.1289 for 5998 observed reflections (I > 2σ(I)). The Co(II) ion is coordinated by two nitrogen atoms of quinoxaline rings from two NITQs and four oxygen atoms from two acac ions to complete a distorted octahedral coordination environment. Compound 1 is further linked into a three-dimensional (3D) supramolecular network by hydrogen-bonding, Cl…O weak contact and π…π stacking interactions. The magnetic measurements show compound 1 exhibits weak ferroma- gnetic interactions.
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