Citation: MIAO Yan-Li, WANG Hong-Bo, GU Chang-Sheng, LI Yong. Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 973-979. doi: 10.14102/j.cnki.0254-5861.2011-0966 shu

Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand

a.
a. College of Science, Guangdong Ocean University, Zhanjiang 524088, China;
b.
b. School of Navigation, Wuhan University of Technology, Wuhan 430063, China

Received Date: 2 September 2015
Available Online: 14 January 2016
Fund Project: This work was supported by Guangdong Ocean University with doctor start-up fund (1112263) (1112263)

Two novel clusters [Mn^III₃(m₃-O)(phendox)₃]X·13H₂O (X = Cl (1), Br (2]) have been obtained from the solvothermal reactions of 1,10-phenanthroline-2,9-dicarbaldehyde dioxime (H₂phendox) with MnCl₂·4H₂O or anhydrous MnBr₂, and their structures were characterized by elemental analysis, FT-IR, XRD, TGA, MS and single-crystal X-ray diffraction. It crystallizes in trigonal, space group P3₁/c. X-ray analysis reveals that the neighbouring [Mn₃(m₃-O)(phendox)₃]⁺ cores are linked by C–H…Cl hydrogen bonds and form an infinite supramolecular chain along the c-axis. Neighbouring chains are packed with each other by off-set p-p interactions of the aromatic rings on phenox^2-. A 3D supramolecular architecture in a honeycomb topology is formed with 1D hexagonal channel in the dimensions of 13Å × 13Å along the c-axis. The gas adsorption studies show that compound 1·13H₂O is stable upon the removal of guest molecules and the desolvated compound absorbed considerable amount of CO₂.
- clusters,
- 1,10-phenanthroline-2,9-dicarbaldehyde dioxime,
- crystal structure,
- gas adsorption
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