Citation:
MIAO Yan-Li, WANG Hong-Bo, GU Chang-Sheng, LI Yong. Syntheses, Structures and Properties of Two Mn(II) Clusters Based on 1,10- Phenanthroline-2,9-dicarbaldehyde Dioxime Ligand[J]. Chinese Journal of Structural Chemistry,
;2016, 35(6): 973-979.
doi:
10.14102/j.cnki.0254-5861.2011-0966
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Two novel clusters [MnIII3(m3-O)(phendox)3]X·13H2O (X = Cl (1), Br (2]) have been obtained from the solvothermal reactions of 1,10-phenanthroline-2,9-dicarbaldehyde dioxime (H2phendox) with MnCl2·4H2O or anhydrous MnBr2, and their structures were characterized by elemental analysis, FT-IR, XRD, TGA, MS and single-crystal X-ray diffraction. It crystallizes in trigonal, space group P31/c. X-ray analysis reveals that the neighbouring [Mn3(m3-O)(phendox)3]+ cores are linked by C–H…Cl hydrogen bonds and form an infinite supramolecular chain along the c-axis. Neighbouring chains are packed with each other by off-set p-p interactions of the aromatic rings on phenox2-. A 3D supramolecular architecture in a honeycomb topology is formed with 1D hexagonal channel in the dimensions of 13Å × 13Å along the c-axis. The gas adsorption studies show that compound 1·13H2O is stable upon the removal of guest molecules and the desolvated compound absorbed considerable amount of CO2.
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