Citation: ZHANG Na-Na, PAN Xiao-Ru, SONG Ming-Jun, WANG Ji-Yang. Growth and Raman Study of Phase Transitions of the KTa_0.63Nb_0.37O₃ Crystal[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 481-486. doi: 10.14102/j.cnki.0254-5861.2011-0921 shu

Growth and Raman Study of Phase Transitions of the KTa_0.63Nb_0.37O₃ Crystal

1.
a College of Chemistry & Chemical and Environmental Engineering, Weifang University, Weifang 261061, China;
2.
b State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China

Received Date: 30 July 2015
Available Online: 20 October 2015
Fund Project: Higher Education and Technology Development Plan of Shandong Province (J15LA09, J14LA5) (BS2015CL012, ZR2014JL029)

The potassium tantalate niobate KTa_0.63Nb_0.37O₃ single crystal with large size and good quality was synthesized by Czochralski method. The crystal composition and structure were determined by electric probe microanalysis (EPMA) and X-ray diffraction (XRD) technique, respectively. The sequence of phase transitions of the as-grown crystal was investigated by Raman scattering technique. What features in the phonon spectrum corresponding to each phase transition, namely cubic to tetragonal (C-T), tetragonal to orthorhombic (T-R) and orthorhombic to rhom-bohedral (O-R), is discussed. Following the features the C-T phase transition point measured is in the vicinity of -40 ℃, and the difference from theoretical value was discussed; T-O phase transition point is at around -130 ℃, while the O-R phase transition point was not obtained due to the band overlapping and experiment limit.
- phase transitions,
- Raman scattering,
- potassium tantalate niobate
1. [1]
  (1) Rytz, D.; Scheel, H. J. Crystal growth of KTa₁_-_xNb_xO₃ (0<x<0.04) solid solutions by a slow-cooling method. J. Cryst. Growth 1982, 3, 468-484.
2. [2]
  (2) Knauss, L. A.; Harshavardhan, K. S.; Christen, H. M.; Zhang, H. Y.; He, X. H.; Shih, Y. H.; Grabowski, K. S.; Knies, D. L. Growth of nonlinear optical thin films of KTa₁_-_xNb_xO₃ on GaAs by pulsed laser deposition for integrated optics. Appl. Phys. Lett. 1998, 3, 3806-3808.
3. [3]
  (3) Ishai, P. B.; Oliveira, C. E. M.; Ryabov, Y.; Feldman, Y.; Agranat, A. J. Glass-forming liquid kinetics manifested in a KTN:Cu crystal. Phys. Rev. B 2004, 13, 132104-132108.
4. [4]
  (4) Wang, J. Y.; Guan, Q. C.; Wei, J. Q.; Liu, Y. G. Growth and characterization of cubic KTa₁_-_xNb_xO₃ crystals. J. Cryst. Growth 1992, 1, 27-36.
5. [5]
  (5) Guan, Q. C.; Wang, J. Y.; Lian, Y. W.; Yang, C. X.; Ye, P. X. Influences of iron doping on the photorefractive properties of KTa_1-xNb_xO₃ crystals. Appl. Phys. Lett.1993, 16, 2186-2188.
6. [6]
  (6) Abdulraheem, Y. M.; Gentile, A. L.; Stafsudd, O. M. The effects of iron as a dopant on the dielectric properties of ferroelectric potassium tantalate niobate. J. Appl. Phys. 2006, 10, 104111.
7. [7]
  (7) Xia, H. R.; Li, L. X.; Wang, J. Y.; Yang, Z. H.; Guan, Q. C. Soft-mode spectroscopy in Fe:KTa_1-xNb_xO₃ crystals. Cryst. Res. Technol. 2000, 10, 1209-1214.
8. [8]
  (8) Xia, H. R.; Li, L. X.; Wang, J. Y.; Liu, Y. G.; Wei, J. Q. Soft mode at the phase transition of KTa_1-xNb_xO₃ single crystal. Chin. J. Light Scatt. 1999, 2, 81-86.
9. [9]
  (9) Bartasyte, A.; Kreisel, J.; Peng, W.; Guilloux-Viry, M. Temperature-dependent Raman scattering of KTa_(1-x)Nb_xO₍₃₎ thin films. Appl. Phys. Lett. 2010, 26, 262903.
10. [10]
  (10) Zhang, N. N.; Wei, R. S.; Wang, J. Y.; Hu, X. B.; Zhang, H. J.; Santos, C. C.; Guedes, I. Phase transition investigation by Raman spectroscopy in highly diluted KTN crystal. J. Alloys Compd. 2012, 53, 14-17.
11. [11]
  (11) Rubin, J. A. Rept. Accession No. AD-764-902, 1973.
12. [12]
  (12) Bouziane, E.; Fontana, M. D. Precursor effects and successive phase transitions in a dilute crystal of KTN. J. Phys-Condens. Matter. 1997, 46, 10249-10260.
13. [13]
  (13) Triebwasser, S. Study of ferroelectric transitions of solid-solution single crystals of KNbO₃-KTaO₃. Phys. Rev. 1959, 1, 63-70.
14. [14]
  (14) Rytz, D.; Hochli, U. T.; Bilz, H. Dielectric susceptibility in quantum ferroelectrics. Phys. Rev. B 1980, 1, 359-364.
15. [15]
  (15) Sommer, D.; Friese, D.; Kleemann, W.; Rytz, D. Ferroelectric phase-transitions and domain relaxation in KTa_1-xNb_xO₃. Ferroelectrics 1991, 3, 231-236.
16. [16]
  (16) Baier-Saip, J. A.; Ramos-Moor, E.; Cabrera, A. L. Raman study of phase transitions in KNbO₃. Solid State Commun. 2005, 6, 367-372.
17. [17]
  (17) Rytz, D.; Chatelain, A.; Hochli, U. T. Elastic properties in quantum ferroelectric KTa_1-xNb_xO₃. Phys. Rev. B 1983, 11, 6830-6840.
18. [18]
  (18) Rankel, S.; Zalar, B.; Laguta, V. V.; Blinc, R.; Toulouse, J. ⁹³Nb NMR study of disorder in KTa_1-xNb_xO₃. Phys. Rev. B 2005, 14, 144110.
19. [19]
  (19) Zhang, N. N.; Pan, X. R.; Song, M. J.; Wang, J. Y. Phase transition investigation of KTa_0.67Nb_0.33O₃ crystal. J. Synth. Cryst. 2015, 9, 2359-2362.
20. [20]
  (20) Matthias, B. T.; Remeika, J. P. Dielectric properties of sodium and potassium niobates. Phys. Rev. 1951, 82, 727-732.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Growth and Raman Study of Phase Transitions of the KTa0.63Nb0.37O3 Crystal

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通讯作者: 陈斌, bchen63@163.com

Growth and Raman Study of Phase Transitions of the KTa_0.63Nb_0.37O₃ Crystal