Citation: KONG Zhi-Guo, GUO Sheng-Nan, YU Miao, FENG Si-Yang, HU Bo. A New Luminescent Cd(II) Coordination Polymer Constructed by Mixed 1,4-Naphthalenedicarboxylate and N-donor Chelating Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(4): 591-596. doi: 10.14102/j.cnki.0254-5861.2011-0908 shu

A New Luminescent Cd(II) Coordination Polymer Constructed by Mixed 1,4-Naphthalenedicarboxylate and N-donor Chelating Ligand

KONG Zhi-Guo ^a,b ,
GUO Sheng-Nan ^a,b ,
YU Miao ^a,b ,
FENG Si-Yang ^a,b ,
HU Bo ^a,b

1.
a Key Laboratory of Preparation and Applications of Environmental Friendly Materials(Jilin Normal University), Ministry of Education, Changchun 130103, China;
2.
b Department of Chemistry, Jilin Normal University, Siping 136000, China

Received Date: 22 July 2015
Available Online: 1 March 2016
Fund Project:

In this work, we synthesized a new two-dimensional Cd(Ⅱ) coordination polymer,[Cd(1,4-NDC)(L)] (1), by using mixed 1,4-naphthalenedicarboxylic acid (1,4-H₂NDC) and typical chelating N-donor ligands 2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f] [1,10]phenanthroline ligand (L). Compound 1 crystallizes in monoclinic, space group P2₁/n with a=12.936(5), b=15.245(5), c=13.499(5) Å, β=105.456(5)o, V=2565.9(16) Å³, Z=4, C₃₁H₁₆CdClFN₄O₄, M_r=675.33, Dc=1.748 g/cm³, F(000)=1344, μ(MoKa)=1.011 mm^-1, R=0.0350 and wR=0.0926. In 1, each 1,4-NDC anion bridges three adjacent Cd(Ⅱ) atoms to give a two-dimensional layer structure. The L ligands are attached on both sides of the layer in chelating coordination modes. In addition, the N-H…O hydrogen bond between L and 1,4-NDC further stabilizes the layer structure of 1. Moreover, the solid state luminescent property of 1 was also investigated at room temperature.
- crystal structure,
- coordination polymer,
- 1,4-naphthalenedicarboxylic acid,
- luminescence
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