Citation: LEI Qian, LIU Qing-Yan, WANG Yu-Ling, CHEN Li-Li, YIN Shun-Gao. Two Three-dimensional Terbium-1,4-benzenedicarboxylate Coordination Polymers: Syntheses, Structures, and Luminescence[J]. Chinese Journal of Structural Chemistry, ;2016, 35(4): 566-576. doi: 10.14102/j.cnki.0254-5861.2011-0901 shu

Two Three-dimensional Terbium-1,4-benzenedicarboxylate Coordination Polymers: Syntheses, Structures, and Luminescence

1.
a Key Laboratory of Small Functional Organic Molecule of Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China;
2.
b State key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received Date: 17 July 2015
Available Online: 10 October 2015
Fund Project: Supported by the NNSFC (21361011) (21361011) the Provincial Natural Science Foundation of Jiangxi (20151BAB203002) (20151BAB203002) the Project of Education Department of Jiangxi Province (GJJ14235) (GJJ14235)the Open Project Program of Key Laboratory of Functional Small Organic Molecule, Ministry of Education, Jiangxi Normal University (KLFS-KF-201412) (KLFS-KF-201412)

Two coordination polymers with 1,4-benzenedicarboxylic acid (H₂BDC) ligand, namely,[Tb₃(BDC)_4.5(H₂O)(DMF)₂]_n (1) and[Tb₂(BDC)₃(H₂O)₂(DMF)₂]_n (2), have been synthesized and characterized. Both compounds crystallize in the triclinic system, space group P1. For compound 1, a=10.8528(5), b=12.2516(5), c=16.9031(7) Å, α=104.462(1), β=93.659(1), γ=101.404(1)°, V=2118.1(2) Å³, Z=2, C₄₂H₃₄N₂O₂₁Tb₃, M_r=1379.47, Dc=2.163 g/cm³, μ=5.045 mm^-1, F(000)=1326, the final R=0.0212 and wR=0.0570 for 8592 observed reflections with I > 2σ(I). For compound 2, a=8.547(1), b=10.170(1), c=11.192(1) Å, α=65.531(1), β=71.886(1), γ=78.796(1)°, V=839.2(2) Å³, Z=1, C₃₀H₃₀N₂O₁₆Tb₂, M_r=992.40, Dc=1.964 g/cm³, μ=4.257 mm^-1, F(000)=482, the final R=0.0220 and wR=0.0649 for 3626 observed reflections with I > 2σ(I). The compounds exhibit different structural topologies depending on the nature of templating agents in the reactions though the templating agents are not incorporated in the final solids. Compound 1 exhibits a three-dimensional (3D) framework based on the rod-shaped terbium-carboxylate building blocks constructed from linear trinuclear Tb₃ units. Compound 2 has a 3D framework containing two interpenetrating pcu topological networks based on the 6-connected dinuclear Tb₂ secondary building units. Photoluminescence studies show both compounds exhibit typical Tb(Ⅲ) luminescence emissions. An efficient ligand-to-Tb(Ⅲ) energy transfer is observed in the emission spectra for both compounds.
- terbium coordination compounds,
- luminescence,
- templates,
- 1,4-benzenedicarboxylate
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1.
沈阳化工大学材料科学与工程学院沈阳 110142