Citation: ZHANG Liang-Liang, DU Shun-Fu, YU Xu-Ying, SUN Dao-Feng. Solvent Dependent Assembly, Structural Diversity and Topology Analysis in Two Novel Ni Coordination Polymers[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 428-436. doi: 10.14102/j.cnki.0254-5861.2011-0880 shu

Solvent Dependent Assembly, Structural Diversity and Topology Analysis in Two Novel Ni Coordination Polymers

1.
College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, China

Received Date: 1 July 2015
Available Online: 15 October 2015
Fund Project: Supported by the National Natural Science Foundation of China (NSFC) (No. 21271117) (NSFC)

Solvent dependent assembly obtained two novel Ni coordination polymers with H₂tbtpa and flexible 1, 2-bix ligand (H₂tbtpa = tetrabromoterephthalic acid and 1, 2-bix = 1, 2-bis(imidazol-1-ylmethyl)benzene), formulated as [Ni_0.5(tbtpa)_0.5(1, 2-bix)·(H₂O)]_n (1) and [Ni(tbtpa)(1, 2-bix)(H₂O)₂]_n (2). They have been structurally characterized by single-crystal and powder X-ray diffraction, elemental analysis, FT-IR spectra and TGA. Compound 1 crystalizes in triclinic, space group P1 with a = 9.0276(4), b = 10.0012(6), c = 11.4955(5) Å, α = 69.121(5), β = 76.398(4), γ = 89.668(4)°, C₃₆H₃₂Br₄NiN₈O₆, M_r = 1051.04, V = 939.05(8) Å³, Z = 1, D_c = 1.859 g·cm^-3, μ = 6.222 mm^-1, F(000) = 520, 8.502≤2θ≤134.16°, λ(CuKα) = 1.54184 Å, T = 294(6) K, the final R = 0.0750, wR = 0.1988 and S = 1.033. Compound 2 crystalizes in triclinic, space group P1 with a = 11.1257(7), b = 11.5062(6), c = 12.3529(4) Å, α = 88.861(3), β = 84.572(4), γ = 64.235(6)°, C₂₂H₁₈Br₄NiN₄O₆, M_r = 812.75, V = 1417.36(1) Å³, Z = 2, D_c = 1.904 g·cm^-3, μ = 7.968 mm^-1, F(000) = 788, 7.2≤2θ≤134.1°, λ(CuKα) = 1.54184 Å, T = 294(6) K, the final R = 0.0414, wR = 0.0865 and S = 1.025. 1 shows a two-dimensional (4, 4)-sql topology and 2 manifests a three-dimensional 6⁵8 CdSO₄ topology coordination polymer network.
- crystal structure,
- 2D sql topology,
- 3D CdS topology,
- solvent dependent assembly
1. [1]
  (1) Eddaoudi, M.; Kim, J.; Rosi, J.; Vodak, N.; Wachter, D.; O'Keeffe, J.; Yaghi, O. M. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Science 2002, 295, 469-472.
2. [2]
  (2) Liu, T. F.; Feng, D.; Chen, Y. P.; Zou, L.; Bosch, M.; Yuan, S.; Wei, Z.; Fordham, S.; Wang, K.; Zhou, H. C. Topology guided design and syntheses of highly stable mesoporous porphyrinic zirconium MOFs with high surface area. J. Am. Chem. Soc. 2015, 137, 413-419.
3. [3]
  (3) Kitagawa, S.; Kitaura, R.; Noro, S. I. Functional porous coordination polymers. Angew. Chem., Int. Ed. 2004, 43, 2334-2375.
4. [4]
  (4) Cui, Y. J.; Yue, Y. F.; Qian, G. D.; Chen, B. L. Luminescent functional metal-organic frameworks. Chem. Rev. 2012, 112, 1126-1162.
5. [5]
  (5) Qian, J. J.; Jiang, F. L.; Zhang, L. J.; Su, K. Z.; Pan, J.; Li, Q. P.; Yuan, D. Q.; Hong, M. C. Unusual pore structure and sorption behaviour in a hexanodal zinc-organic framework material. Chem. Commun. 2014, 50, 1678-1681
6. [6]
  (6) Chen, W. T.; Hu, R. H.; Xu, Y. P.; Luo, Q. Y.; Dai, Y. K.; Huang, S. L.; Guo, P. Y. Photophysical and electrochemical properties of a novel lanthanide tetra(4-sulfonatophenyl)porphyrin. J. Iran. Chem. Soc. 2015, 12, 937-942.
7. [7]
  (7) Chen, W. T.; Huang, J. G.; Luo, Q. Y.; Xu, Y. P.; Fu, H. R. A novel terbium-cobalt tetra(4-sulfonatophenyl)porphyrin: synthesis, structure and photophysical and electrochemical properties. J. Porphyr. Phthalocya 2015, 19, 154-159.
8. [8]
  (8) Chen, W. T.; Hu, R. H.; Luo, Z. G.; Chen, H. L.; Liu, J. A new 3-D lanthanide porphyrin: synthesis, structure and photophysical properties. Chin. J. Struct. Chem. 2015, 34, 279-284.
9. [9]
  (9) Liu, F.; Zhang, L.; Wang, R.; Sun, J.; Yang, J.; Chen, Z.; Wang, X.; Sun, D. Five MOFs with different topologies based on anthracene functionalized tetracarboxylic acid: syntheses, structures, and properties. CrystEngComm. 2014, 16, 2917-2928.
10. [10]
  (10) Yang, J.; Wang, X. Q.; Wang, R. M.; Zhang, L. L.; Liu, F. L.; Dai, F. N.; Sun, D. F. Syntheses, crystal structures, and properties of two 2-fold interpenetrating metal-organic frameworks based on a trigonal rigid ligand. Cryst. Growth Des. 2014, 14, 6521-6527.
11. [11]
  (11) Zhang, L.; Liu, F.; Guo, Y.; Wang, X.; Guo, J.; Wei, Y.; Chen, Z.; Sun, D. Crystal structure diversities based on 4, 4'-(2, 3, 6, 7-tetramethoxyanthracene-9, 10-diyl)dibenzoic acid: from 2D layer to 3D net framework. Cryst. Growth Des. 2012, 12, 6215-6222.
12. [12]
  (12) Zheng, S.; Wu, T.; Zhang, J.; Chow, M.; Nieto, R; Feng, P.; Bu, X. Porous metal carboxylate boron imidazolate frameworks. Angew. Chem. Int. Ed. 2010, 49, 5362-5366.
13. [13]
  (13) Wang, R. M.; Wang, Z. Y.; Xu, Y. W.; Dai, F. N.; Zhang, L. L.; Sun, D. F. Porous zirconium metal-organic framework constructed from 2D- > 3D interpenetration based on a 3, 6-connected kgd net. Inorg. Chem. 2014, 53, 7086-7088.
14. [14]
  (14) Sheldrick, G. M. SHELXS-97, Program for X-ray Crystal Structure Solution. University of Göttingen, Germany 1997.
15. [15]
  (15) Sheldrick, G. M. SHELXL-97, Program for X-ray Crystal Structure Refinement. University of Göttingen, Germany 1997.
16. [16]
  (16) Spek, A. L. Implemented as the PLATON Procedure, a Multipurpose Crystallographic Tool. Utrecht University, Utrecht, The Netherlands 1998.
17. [17]
  (17) Shao, Y.; Qin, L.; Yu, S. Y. 2-D Metal organic structure based on dipyrazolate ligand through Ni…N and Ni…H-N interactions. Chin. J. Struct. Chem. 2012, 11, 1545-1548.
18. [18]
  (18) Hu, J. S.; Huang, X. H.; Pan, C. L.; Zhang, L. Photochemical and magnetic properties of seven new metal-organic frameworks constructed by flexible tetrapyridines and V-shaped polycarboxylate acids. Cryst. Growth Des. 2015, 15, 2272-2281.
19. [19]
  (19) Tomar, K.; Rajak, R.; Sanda, S.; Konar, S. Synthesis and characterization of polyhedral-based metal-organic frameworks using a flexible bipyrazole ligand: topological analysis and sorption property studies. Cryst. Growth Des. 2015, 15, 2732-2741.
20. [20]
  (20) Zhang, S.; Liu, X. Y.; Yang, Q.; Wei, Q.; Xie, G.; Chen, S. P. Mixed-metal-organic frameworks (M'MOFs) from 1D to 3D based on the “organic” connectivity and the inorganic connectivity: syntheses, structures and magnetic properties. CrystEngComm. 2015, 17, 3312-3324.
21. [21]
  (21) Zhao, J. W.; Shi, D. Y.; Chen, L. J.; Ma, P. T.; Wang, J. P.; Niu, J. Y. Two 1-D multi-nickel substituted arsenotungstate aggregates. CrystEngComm. 2011, 13, 3462-3469.
22. [22]
  (22) Blatov, V. A. Multipurpose crystallochemical analysis with the program package TOPOS. IUCr CompComm Newsletter 2006, 7, 4-38. TOPOS is available at http://www.topos.ssu.samara.ru.
1. [1]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
2. [2]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
3. [3]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
4. [4]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
5. [5]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
6. [6]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
7. [7]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
8. [8]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
9. [9]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
10. [10]
  Jie Wu , Xiaoqing Yu , Guoxing Li , Su Chen . Engineering particles towards 3D supraballs-based passive cooling via grafting CDs onto colloidal photonic crystals. Chinese Chemical Letters, 2024, 35(4): 109234-. doi: 10.1016/j.cclet.2023.109234
11. [11]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
12. [12]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
13. [13]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
14. [14]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845
15. [15]
  Yuexi Guo , Zhaoyang Li , Jingwei Dai . Charlie and the 3D Printing Chocolate Factory. University Chemistry, 2024, 39(9): 235-242. doi: 10.3866/PKU.DXHX202309067
16. [16]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580
17. [17]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
18. [18]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
19. [19]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
20. [20]
  Chaozheng He , Jia Wang , Ling Fu , Wei Wei . Nitric oxide assists nitrogen reduction reaction on 2D MBene: A theoretical study. Chinese Chemical Letters, 2024, 35(5): 109037-. doi: 10.1016/j.cclet.2023.109037

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(708)
HTML views(49)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142