Citation: ZHANG Liang-Liang, DU Shun-Fu, YU Xu-Ying, SUN Dao-Feng. Solvent Dependent Assembly, Structural Diversity and Topology Analysis in Two Novel Ni Coordination Polymers[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 428-436. doi: 10.14102/j.cnki.0254-5861.2011-0880 shu

Solvent Dependent Assembly, Structural Diversity and Topology Analysis in Two Novel Ni Coordination Polymers

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College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, China

Received Date: 1 July 2015
Available Online: 15 October 2015
Fund Project: Supported by the National Natural Science Foundation of China (NSFC) (No. 21271117) (NSFC)

Solvent dependent assembly obtained two novel Ni coordination polymers with H₂tbtpa and flexible 1, 2-bix ligand (H₂tbtpa = tetrabromoterephthalic acid and 1, 2-bix = 1, 2-bis(imidazol-1-ylmethyl)benzene), formulated as [Ni_0.5(tbtpa)_0.5(1, 2-bix)·(H₂O)]_n (1) and [Ni(tbtpa)(1, 2-bix)(H₂O)₂]_n (2). They have been structurally characterized by single-crystal and powder X-ray diffraction, elemental analysis, FT-IR spectra and TGA. Compound 1 crystalizes in triclinic, space group P1 with a = 9.0276(4), b = 10.0012(6), c = 11.4955(5) Å, α = 69.121(5), β = 76.398(4), γ = 89.668(4)°, C₃₆H₃₂Br₄NiN₈O₆, M_r = 1051.04, V = 939.05(8) Å³, Z = 1, D_c = 1.859 g·cm^-3, μ = 6.222 mm^-1, F(000) = 520, 8.502≤2θ≤134.16°, λ(CuKα) = 1.54184 Å, T = 294(6) K, the final R = 0.0750, wR = 0.1988 and S = 1.033. Compound 2 crystalizes in triclinic, space group P1 with a = 11.1257(7), b = 11.5062(6), c = 12.3529(4) Å, α = 88.861(3), β = 84.572(4), γ = 64.235(6)°, C₂₂H₁₈Br₄NiN₄O₆, M_r = 812.75, V = 1417.36(1) Å³, Z = 2, D_c = 1.904 g·cm^-3, μ = 7.968 mm^-1, F(000) = 788, 7.2≤2θ≤134.1°, λ(CuKα) = 1.54184 Å, T = 294(6) K, the final R = 0.0414, wR = 0.0865 and S = 1.025. 1 shows a two-dimensional (4, 4)-sql topology and 2 manifests a three-dimensional 6⁵8 CdSO₄ topology coordination polymer network.
- crystal structure,
- 2D sql topology,
- 3D CdS topology,
- solvent dependent assembly
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沈阳化工大学材料科学与工程学院沈阳 110142