Citation:
ZHANG Liang-Liang, DU Shun-Fu, YU Xu-Ying, SUN Dao-Feng. Solvent Dependent Assembly, Structural Diversity and Topology Analysis in Two Novel Ni Coordination Polymers[J]. Chinese Journal of Structural Chemistry,
;2016, 35(3): 428-436.
doi:
10.14102/j.cnki.0254-5861.2011-0880
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Solvent dependent assembly obtained two novel Ni coordination polymers with H2tbtpa and flexible 1, 2-bix ligand (H2tbtpa = tetrabromoterephthalic acid and 1, 2-bix = 1, 2-bis(imidazol-1-ylmethyl)benzene), formulated as [Ni0.5(tbtpa)0.5(1, 2-bix)·(H2O)]n (1) and [Ni(tbtpa)(1, 2-bix)(H2O)2]n (2). They have been structurally characterized by single-crystal and powder X-ray diffraction, elemental analysis, FT-IR spectra and TGA. Compound 1 crystalizes in triclinic, space group P1 with a = 9.0276(4), b = 10.0012(6), c = 11.4955(5) Å, α = 69.121(5), β = 76.398(4), γ = 89.668(4)°, C36H32Br4NiN8O6, Mr = 1051.04, V = 939.05(8) Å3, Z = 1, Dc = 1.859 g·cm-3, μ = 6.222 mm-1, F(000) = 520, 8.502≤2θ≤134.16°, λ(CuKα) = 1.54184 Å, T = 294(6) K, the final R = 0.0750, wR = 0.1988 and S = 1.033. Compound 2 crystalizes in triclinic, space group P1 with a = 11.1257(7), b = 11.5062(6), c = 12.3529(4) Å, α = 88.861(3), β = 84.572(4), γ = 64.235(6)°, C22H18Br4NiN4O6, Mr = 812.75, V = 1417.36(1) Å3, Z = 2, Dc = 1.904 g·cm-3, μ = 7.968 mm-1, F(000) = 788, 7.2≤2θ≤134.1°, λ(CuKα) = 1.54184 Å, T = 294(6) K, the final R = 0.0414, wR = 0.0865 and S = 1.025. 1 shows a two-dimensional (4, 4)-sql topology and 2 manifests a three-dimensional 658 CdSO4 topology coordination polymer network.
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