Citation: ZHANG Liang-Liang, DU Shun-Fu, YU Xu-Ying, SUN Dao-Feng. Solvent Dependent Assembly, Structural Diversity and Topology Analysis in Two Novel Ni Coordination Polymers[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 428-436. doi: 10.14102/j.cnki.0254-5861.2011-0880 shu

Solvent Dependent Assembly, Structural Diversity and Topology Analysis in Two Novel Ni Coordination Polymers

1.
College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, China

Received Date: 1 July 2015
Available Online: 15 October 2015
Fund Project: Supported by the National Natural Science Foundation of China (NSFC) (No. 21271117) (NSFC)

Solvent dependent assembly obtained two novel Ni coordination polymers with H₂tbtpa and flexible 1, 2-bix ligand (H₂tbtpa = tetrabromoterephthalic acid and 1, 2-bix = 1, 2-bis(imidazol-1-ylmethyl)benzene), formulated as [Ni_0.5(tbtpa)_0.5(1, 2-bix)·(H₂O)]_n (1) and [Ni(tbtpa)(1, 2-bix)(H₂O)₂]_n (2). They have been structurally characterized by single-crystal and powder X-ray diffraction, elemental analysis, FT-IR spectra and TGA. Compound 1 crystalizes in triclinic, space group P1 with a = 9.0276(4), b = 10.0012(6), c = 11.4955(5) Å, α = 69.121(5), β = 76.398(4), γ = 89.668(4)°, C₃₆H₃₂Br₄NiN₈O₆, M_r = 1051.04, V = 939.05(8) Å³, Z = 1, D_c = 1.859 g·cm^-3, μ = 6.222 mm^-1, F(000) = 520, 8.502≤2θ≤134.16°, λ(CuKα) = 1.54184 Å, T = 294(6) K, the final R = 0.0750, wR = 0.1988 and S = 1.033. Compound 2 crystalizes in triclinic, space group P1 with a = 11.1257(7), b = 11.5062(6), c = 12.3529(4) Å, α = 88.861(3), β = 84.572(4), γ = 64.235(6)°, C₂₂H₁₈Br₄NiN₄O₆, M_r = 812.75, V = 1417.36(1) Å³, Z = 2, D_c = 1.904 g·cm^-3, μ = 7.968 mm^-1, F(000) = 788, 7.2≤2θ≤134.1°, λ(CuKα) = 1.54184 Å, T = 294(6) K, the final R = 0.0414, wR = 0.0865 and S = 1.025. 1 shows a two-dimensional (4, 4)-sql topology and 2 manifests a three-dimensional 6⁵8 CdSO₄ topology coordination polymer network.
- crystal structure,
- 2D sql topology,
- 3D CdS topology,
- solvent dependent assembly
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沈阳化工大学材料科学与工程学院沈阳 110142