Citation: LIU Ting-Yu, CHEN Yi-Ping, HUANG Xiao-Hui, CHEN Ning, HUANG Meng-Meng, SUN Yan-Qiong. Comparing the Structures of Two Allomorphic Polyoxotungstates and the Difference in Weak Interactions by Thermal-dependent 2D-COS IR to Identify[J]. Chinese Journal of Structural Chemistry, ;2015, 34(11): 1665-1674. doi: 10.14102/j.cnki.0254-5861.2011-0879 shu

Comparing the Structures of Two Allomorphic Polyoxotungstates and the Difference in Weak Interactions by Thermal-dependent 2D-COS IR to Identify

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a. College of Chemistry of Chemistry, Fuzhou University, Fuzhou 350108, China;
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b. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: CHEN Yi-Ping,
Received Date: 1 June 2015
Available Online: 16 September 2015
Fund Project: This work was supported by the NNSFC (No. 21473030, 1371033) (No. 21473030, 1371033) Fujian Provincial Natural Science Foundation (2013J01042) (2013J01042)

A three-dimensional (3D) Keggin-type heteropolytungstate{Zn(phen)₃}₃[ZnW₁₂O₄₀]·9H₂O 1 (phen=1,10-phenanthroline) has been synthesized through a conventional hydrothermal synthesis and was characterized by X-ray single-crystal diffraction analysis, X-ray powder diffraction (XRD), IR, UV-DRS, thermogravimetric analysis (TGA), thermal-dependent 2D-IR correlation spectroscopy (2D-COS IR) and Raman spectrum. Crystal data for compound 1: trigonal system, space group R3 with a=b=25.268(4), c=17.462(5) Å, γ=120°, V=9655(4) Å³ and Z=3. Compound 1 is allomorphic to {Co(phen)₃}₃[CoW₁₂O₄₀]·9H₂O 2, which has been reported by Feng Chai et al. In compound 2, its prominent feature is that the decisive role of water molecules (O-H…O) builds a 3D supramolecular structure. However, in the structure of compound 1, the interlayer space is filled by Zn(phen)₃]²⁺ cations which linked the layers via C-H…O hydrogen bonding interactions to construct a three-dimensional framework. Two compounds are different in weak interactions, so we identify them by Thermal-dependent 2D-COS IR. Moreover, the fluorescence of compound 1 was also described.
- Keggin-type polyoxotungstates,
- hydrothermal synthesis,
- thermal-dependent 2D-IR correlation spectroscopy,
- Raman spectra,
- luminescence
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