Citation: ZHOU Liang-Liang, DING Ling, WEI Kun-Yu(魏坤宇), SUN Yan-Qiong, CHEN Yi-Ping. Novel Lanthanide Cluster Polymers Based on Cubane-like [Ln₄(OH)₄]⁸⁺ Clusters and Sulfate Anions[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 375-382. doi: 10.14102/j.cnki.0254-5861.2011-0876 shu

Novel Lanthanide Cluster Polymers Based on Cubane-like [Ln₄(OH)₄]⁸⁺ Clusters and Sulfate Anions

1.
a College of Chemistry, Fuzhou University, Fuzhou 350116, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: SUN Yan-Qiong,
Received Date: 30 June 2015
Available Online: 14 October 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21473030) (No. 21473030) the Natural Science Foundation of Fujian Province (No. 2013J01041) (No. 2013J01041)the Foundation of State Key Laboratory of Structural Chemistry (No. 20130012) (No. 20130012)

Two lanthanide-oxo-cluster polymers were synthesized by hydrothermal reaction using Ln₂O₃ as initial lanthanide materials: [Ln₄(SO₄)₄(OH)₄(H₂O)₇]·4H₂O (Ln = Er 1, Ho 2), and characterized by PXRD, IR spectra, X-ray single-crystal diffraction, 2D IR correlation spectra and UV-visible absorption spectra. Single-crystal X-ray analyses reveal that compounds 1 and 2 are isostructural, and they are both crystallized in the orthorhombic system Pccn space group. Compound 1 is a 3D lanthanide cluster polymer based on tetranuclear cubane-like [Er₄(μ₃-OH)₄]⁸⁺ cations and SO₄^2- anions. The overall structure of 1 can be assigned to 6-connected pcu-type topology with the point symbol of (4¹².6³).
- lanthanide cluster polymer,
- crystal structure,
- tetranuclear lanthanide-oxo-clusters,
- sulfate anion
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Novel Lanthanide Cluster Polymers Based on Cubane-like [Ln4(OH)4]8+ Clusters and Sulfate Anions

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通讯作者: 陈斌, bchen63@163.com

Novel Lanthanide Cluster Polymers Based on Cubane-like [Ln₄(OH)₄]⁸⁺ Clusters and Sulfate Anions