Citation: LU Wen-Guan, WANG Xiao-Bing, LIU Hong-Wen, HONG Xian-Lan. Two Coordination Polymers Constructed by Cd(II) and Zn(II) with in situ Generated 5-(3-Pyridyl)tetrazolate Ligand: Syntheses, Crystal Structures and Luminescence Properties[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 383-391. doi: 10.14102/j.cnki.0254-5861.2011-0859 shu

Two Coordination Polymers Constructed by Cd(II) and Zn(II) with in situ Generated 5-(3-Pyridyl)tetrazolate Ligand: Syntheses, Crystal Structures and Luminescence Properties

1.
Department of Chemistry, Shaoguan University, Shaoguan 512005, China

Received Date: 18 June 2015
Available Online: 23 October 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21071099) (No. 21071099) Natural Science Foundation of Guangdong Province (No. 2015A030313750) (No. 2015A030313750)

Hydrothermal reactions of 3-cyanopyridine and NaN₃ with ZnCl₂ or CdCl₂·5/2H₂O in the presence of 1, 4-benzenedicarboxylic acid (H₂bdc) yielded two new coordination polymers, {[Zn(3-ptz)(bdc)_0.5(H₂O)₂]_n·2H₂O}_n (1) and [Cd₂(3-ptz)₂Cl₂]_n (2), based on in situ synthesized 5-(3-pyridyl)tetrazolate (3-ptz^-) organic ligand. They have been structurally characterized by elemental analysis (EA), infrared spectroscopy (IR) and single-crystal/powder X-ray diffraction (PXRD). In 1, two Zn(II) ions are linked together through two µ₂-(3-ptz^-) ligands to form a dimeric unit of [Zn(µ₂-3-ptz)(H₂O)₂]₂²⁺, which is further connected with other equivalent units by µ₂-bdc^2- spacers, resulting in an infinite 1D polymeric chain of [Zn₂(3-ptz)₂(H₂O)₂(bdc)]_n, and then strong hydrogen bonding interactions extend these 1D chains into a 3D supramolecular structure. In 2, the Cd(II) ions are connected through µ₄-(3-ptz^-) ligands and Cl^- anions, leading to infinite 2D layers of [Cd₂(3-ptz)Cl₂]_nⁿ⁺, which are further linked by another µ₄-(3-ptz^-) pillared ligand to form a 3D layered-pillared framework architecture of [Cd₂(3-ptz)₂Cl₂]_n. Furthermore, thermal stability of these compounds was measured by thermogravimetric analysis (TGA) and their photoluminescent properties were also investigated in the solid state at room temperature.
- coordination polymers,
- 5-(3-pyridyl)tetrazole,
- crystal structure,
- fluorescence
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