Citation: WANG Yu-Fang, SUN Xiao-Yuan, GENG Jun-Lei. Synthesis, Crystal Structure and Fluorescent Properties of a Cadmium(II) Complex with 3-(Pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 397-403. doi: 10.14102/j.cnki.0254-5861.2011-0853 shu

Synthesis, Crystal Structure and Fluorescent Properties of a Cadmium(II) Complex with 3-(Pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole

1.
a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China;
2.
b School of Chemical Engineering, Guizhou University of Engineering Science, Bijie 551700, China

Received Date: 16 June 2015
Available Online: 22 October 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21271098) (No. 21271098)

Compound [Cd_1.5(ppt)Br₂(H₂O)]_2n (1), where Hppt = 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1, 2, 4-triazole, has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectra, powder XRD, and X-ray diffraction. Compound 1 crystallizes in the triclinic system, space group P1 with a = 7.4402(6), b = 8.0570(7), c = 12.8674(11) Å, a = 89.7300(10), b = 89.8570(10), g = 68.3910(10)°, V = 717.13(10) Å³, Z = 1, D_c = 2.638 g/cm³, μ = 7.824 mm^-1, F(000) = 534, the final R = 0.0324 and wR = 0.1084 for 2324 observed reflections with I > 2s(I). X-ray diffraction analyses revealed that complex 1 is a 2D layered coordination polymer constructed from the linkage of [Cd₃(μ-Br)₄] trinuclear units with ppt^- spacers, and a 3D supramolecular architecture is further assembled in 1 via hydrogen-bonding contacts. Fluorescence measurements show that 1 has medium fluorescent emission at 450 nm.
- trinuclear unit,
- crystal structure,
- fluorescent
1. [1]
  (1) Chakrabarty, R.; Mukherjee, P. S.; Stang, P. J. Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles. Chem. Rev. 2011, 111, 6810-6918.
2. [2]
  (2) Ito, H.; Ikeda, M.; Hasegawa, T.; Furusho, Y.; Yashima, E. Synthesis of complementary double-stranded helical oligomers through chiral and achiral amidinium-carboxylate salt bridges and chiral amplification in their double-helix formation. J. Am. Chem. Soc. 2011, 133, 3419-3432.
3. [3]
  (3) Du, M.; Li, C. P.; Chen, M.; Ge, Z. W.; Wang, X.; Wang, L.; Liu, C. S. Divergent kinetic and thermodynamic hydration of a porous Cu(II) coordination polymer with exclusive CO₂ sorption selectivity. J. Am. Chem. Soc. 2014, 136, 10906-10909.
4. [4]
  (4) Du, M.; Chen, M.; Yang, X. G.; Wen, J.; Wang, X.; Fang, S. M.; Liu, C. S. A channel-type mesoporous In(III)-carboxylate coordination framework with high physicochemical stability for use as an electrode material in supercapacitors. J. Mater. Chem. A 2014, 2, 9828-9834.
5. [5]
  (5) Li, C. P.; Chen, J.; Liu, C. S.; Du, M. Dynamic structural transformations of coordination supramolecular systems upon exogenous stimulation. Chem. Commun. 2015, 51, 2768-2781.
6. [6]
  (6) Jiang, H. L.; Makal, T. A.; Zhou, H. C. Interpenetration control in metal-organic frameworks for functional applications. Coord. Chem. Rev. 2013, 257, 2232-2249.
7. [7]
  (7) Li, C. P.; Du, M. Role of solvents in coordination supramolecular systems. Chem. Commun. 2011, 47, 5958-5972.
8. [8]
  (8) Kitagawa, S.; Matsuda, R. Chemistry of coordination space of porous coordination polymers. Coord. Chem. Rev. 2007, 251, 2490-2509.
9. [9]
  (9) Zhao, N.; Sun, F. X.; He, H. M.; Jia, J. T.; Zhu, G. S. Solvent-induced single crystal to single crystal transformation and complete metal exchange of a pyrene-based metal-organic framework. Cryst. Growth Des. 2014, 14, 1738-1743.
10. [10]
  (10) Jiang, L.; Wang, Z.; Bai, S. Q.; Andy Hor, T. S. Tuning the Zn(II) coordination assembly by adjusting the spacers of 2-pyridylthiomethyl functionalized 1, 2, 3-triazoles. CrystEngComm. 2013, 15, 10451-10458.
11. [11]
  (11) Moliner, N.; Gaspar, A. B.; Munoz, M. C.; Niel, V.; Cano, J.; Real. J. A. Light- and thermal-induced spin crossover in {Fe(abpt)₂[N(CN)₂]₂}. Synthesis, structure, magnetic properties, and high-spin ↔ low-spin relaxation studies. Inorg. Chem. 2001, 40, 3986-3991.
12. [12]
  (12) Chen, K. J.; Lin, R. B.; Liao, P. Q.; He, C. T.; Lin, J. B.; Xue, W.; Zhang, Y. B.; Zhang, J. P.; Chen, X. M. New Zn-aminotriazolate-dicarboxylate frameworks: synthesis, structures, and adsorption properties. Cryst. Growth Des. 2013, 13, 2118-2123.
13. [13]
  (13) Fang, Z. L.; He, J. G.; Zhang, Q. S.; Zhang, Q. K.; Wu, X. Y.; Yu, R. M.; Lu. C. Z. pH-Controlled construction of Cu(I) coordination polymers: in situ transformation of ligand, network topologies, and luminescence and UV-vis-NIR absorption properties. Inorg. Chem. 2011, 50, 11403-11411.
14. [14]
  (14) van Koningsbruggen, P. J.; Gatteschi, D.; de Graaff, R. A. G.; Haasnoot, J. G.; Reedijk, J.; Zanchini, C. Isotropic and anisotropic magnetic exchange interactions through .mu.-N1, N2 1, 2, 4-triazole and .mu.-sulfato bridges: X-ray crystal structure, magnetic properties, and single-crystal EPR study of (.mu.-4-amino-3, 5-bis(pyridin-2-yl)-1, 2, 4-triazole-N', N1, N2, N”)(.mu.-sulfato-O, O')[(sulfato-O)aquacopper(II)]triaquacopper(II) hydrate. Inorg. Chem. 1995, 34, 5175-5182.
15. [15]
  (15) Liu, D.; Li, M.; Li, D. Reversible solid-gas chemical equilibrium between a 0-periodic deformable molecular tecton and a 3-periodic coordination architecture. Chem. Commun. 2009, 6943-6945.
16. [16]
  (16) Dong, W. W.; Li, D. S.; Zhao, J.; Duan, Y. P.; Bai, L.; Yang, J. J. Unique 3D Co^II/Zn^II-coordination polymers with (3, 4, 5)-connected self-penetrating topology: syntheses, topological structures, luminescent and magnetic properties. RSC Adv. 2012, 2, 11219-11222.
17. [17]
  (17) Wang, Y. F.; Li, Z.; Sun, Y. C.; Zhao, J. S.; Wang, L. Y. Structural modulation and properties of four cadmium(II) coordination architectures based on 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1, 2, 4-triazole and aromatic polycarboxylate ligands. CrystEngComm. 2013, 15, 9980-9987.
18. [18]
  (18) Sheldrick, G. M. SHELXS 97, Program for the Solution of Crystal Structures. University of Göttingen, Germany 1997.
19. [19]
  (19) Sheldrick, G. M. SHELXL 97, Program for the Refinement of Crystal Structures. University of Göttingen, Germany 1997.
20. [20]
  (20) Xu, B.; Li, Z. W.; Jiang, Y.; Li, C. C. A luminescent Cd(II) coordination polymer constructed from isophthalic acid and 1, 3-bis-(4-pyridyl) propane. Chin. J. Struct. Chem. 2015, 34, 925-930.
21. [21]
  (21) Zhai, Q. G.; Wu, X. Y.; Chen, S. M.; Lu, C. Z.; Yang, W. B. Construction of Cd/Zn(II)-1, 2, 4-triazolate coordination complexes via changing substituents and anions. Cryst. Growth Des. 2006, 6, 2126-2135.
22. [22]
  (22) Zhang, R. B.; Li, Z. J.; Qin, Y. Y.; Cheng, J. K.; Zhang, J.; Yao, Y. G. Synthesis, structure, and physical properties of a new anions-controlled Cd(II)-guanazole (3, 5-diamino-1, 2, 4-triazole) hybrid family. Inorg. Chem. 2008, 47, 4861-4876.
23. [23]
  (23) Cheng, P. C.; Kuo, P. T.; Liao, Y. H.; Xie, M. Y.; Hsu, W.; Chen, J. D. Ligand-isomerism controlled structural diversity of Zn(II) and Cd(II) coordination polymers from mixed dipyridyladipoamide and benzenedicarboxylate ligands. Cryst. Growth Des. 2013, 13, 623-632.
24. [24]
  (24) Tao, Y.; Li. J. R.; Yu, Q.; Song, W. C.; Tong X. L.; Bu, X. H. Coordination architectures of 2-(1H-tetrazol-5-yl) pyrazine with group IIB metal ions: luminescence and structural dependence on the metal ions and preparing conditions. CrystEngComm. 2008, 10, 699-705.
25. [25]
  (25) Yu, G.; Yin, S.; Liu, Y.; Shuai, Z.; Zhu, D. Structures, electronic states, and electroluminescent properties of a zinc(II) 2-(2-hydroxyphenyl)benzothiazolate complex. J. Am. Chem. Soc. 2003, 125, 14816-14824.
26. [26]
  (26) Tao, J.; Tong, M. L.; Shi, J. X.; Chen, X. M.; Ng, S. W. Blue photoluminescent zinc coordination polymers with supertetranulear cores. Chem. Commun. 2000, 2043-2044.
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1.
沈阳化工大学材料科学与工程学院沈阳 110142