Citation: WANG Yu-Fang, SUN Xiao-Yuan, GENG Jun-Lei. Synthesis, Crystal Structure and Fluorescent Properties of a Cadmium(II) Complex with 3-(Pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 397-403. doi: 10.14102/j.cnki.0254-5861.2011-0853 shu

Synthesis, Crystal Structure and Fluorescent Properties of a Cadmium(II) Complex with 3-(Pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole

1.
a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China;
2.
b School of Chemical Engineering, Guizhou University of Engineering Science, Bijie 551700, China

Received Date: 16 June 2015
Available Online: 22 October 2015
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21271098) (No. 21271098)

Compound [Cd_1.5(ppt)Br₂(H₂O)]_2n (1), where Hppt = 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1, 2, 4-triazole, has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectra, powder XRD, and X-ray diffraction. Compound 1 crystallizes in the triclinic system, space group P1 with a = 7.4402(6), b = 8.0570(7), c = 12.8674(11) Å, a = 89.7300(10), b = 89.8570(10), g = 68.3910(10)°, V = 717.13(10) Å³, Z = 1, D_c = 2.638 g/cm³, μ = 7.824 mm^-1, F(000) = 534, the final R = 0.0324 and wR = 0.1084 for 2324 observed reflections with I > 2s(I). X-ray diffraction analyses revealed that complex 1 is a 2D layered coordination polymer constructed from the linkage of [Cd₃(μ-Br)₄] trinuclear units with ppt^- spacers, and a 3D supramolecular architecture is further assembled in 1 via hydrogen-bonding contacts. Fluorescence measurements show that 1 has medium fluorescent emission at 450 nm.
- trinuclear unit,
- crystal structure,
- fluorescent
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1.
沈阳化工大学材料科学与工程学院沈阳 110142