Citation: MA Fa-Xue, ZHAO Dan, ZHANG Rong-Hua, LI Fei-Fei, ZHANG Ai-Yun. A New Coordination Polymer Pb(C₁₂H₆O₄): Structure Resolution of Non-merohedral Twinning Crystal[J]. Chinese Journal of Structural Chemistry, ;2016, 35(3): 437-441. doi: 10.14102/j.cnki.0254-5861.2011-0846 shu

A New Coordination Polymer Pb(C₁₂H₆O₄): Structure Resolution of Non-merohedral Twinning Crystal

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: ZHAO Dan,
Received Date: 13 June 2015
Available Online: 22 December 2015
Fund Project: This work was supported by the National Science Foundation of China (No. 21201056) (No. 21201056)

Hydrothermal reaction of naphthalene-1, 8-dicarboxylate with PbCl₂ leads to a new coordination polymer compound, Pb(C₁₂H₆O₄). Single-crystal X-ray diffraction analysis reveals that it crystallizes in monoclinic, space group P2₁/c with a = 13.1648(18), b = 5.3881(8), c = 14.599(2) Å, β = 95.759(2)°, V = 1030.3(3) Å³, Z = 4, M_r = 384.32, D_c = 2.7167 g/cm³, F(000) = 768, μ(MoKα) = 16.37 mm^-1, R = 0.043 and wR = 0.097. The structure of Pb(C₁₂H₆O₄) was refined by two components non-merohedral twinning model with the twin law of (-1000-100.22401) and twinning ratio of 0.736:0.264. In this structure, the Pb atoms are surrounded by five O atoms from ligands into PbO₅ polyhedra, which are further interconnected to form a 2D layer structure parallel to the bc-plane.
- coordination polymer,
- naphthalene-1,
- 8-dicarboxylate,
- non-merohedral twinning
1. [1]
  (1) Sheldrick, G. M. A short history of SHELX. Acta Cryst. A 2008, 64, 112-122.
2. [2]
  (2) Grimmer, H.; Nespolo, M. Geminography: the crystallography of twins. Z. Kristallogr. 2006, 221, 28-50.
3. [3]
  (3) Koch, E. Twinning, in: E. Prince (Ed.), International Tables for Crystallography, Volume C: Mathematical, Physical and Chemical Tables, Springer Inc., Netherlands 2006, pp 10-14.
4. [4]
  (4) Hostettler, M.; Schwarzenbach, D. The structure of orange HgI₂. II. Diamond-type structure and twinning. Acta Cryst. B 2002, 58, 914-920.
5. [5]
  (5) Ng Seik, W. Indexing non-merohedrally twinned crystals by Bruker's APEX2 and agilent's CrysAlis (PRO), an example of a crystal structure that can be refined through either the PLATON route or the 'HKLF 5' route, and, simultaneous data collection of two crystals in a two-in-one run. Chin. J. Struct. Chem. 2014, 33, 294-303.
6. [6]
  (6) Zhang, W. H.; Ng, S. W. Non-merohedrally twinned crystal structure of the co-crystal ethyl 6-(2-5-(ethoxycarbonyl)-pyridin-2-yl-1, 2-dihydroxyethyl)pyridine-3-carboxylateethyl 6-(2-5-(ethoxycarbonyl)pyridin-2-yl-2-hydroxyacetyl)pyridine-3-carboxy late (0.69/0.31). Chin. J. Struc. Chem. 2013, 32, 1159-1162.
7. [7]
  (7) Reger, D. L.; Little, C. A.; Young, V. G.; Pink, M. Variable-temperature X-ray structural investigation of {Fe[HC(3, 5-Me₂pz)₃]₂}(BF₄)₂ (pz = pyrazolyl ring): observation of a thermally induced spin state change from all high spin to an equal high spin-low spin mixture, concomitant with the onset of nonmerohedral twinning. Inorg. Chem. 2001, 40, 2870-2874.
8. [8]
  (8) Bruker. APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA 2013.
9. [9]
  (9) Spek, A. L. PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, The Netherlands 2005.
10. [10]
  (10) Bruker AXS Inc. TWINABS. Bruker AXS Ins., Madison, Wisconsin, USA 2009.
11. [11]
  (11) Sheldrick, G. M. SADABS. University of G ttingen, Germany 1996.
12. [12]
  (12) Chen, J.; Zhang, Q.; Liu, Z. F.; Wang, S. H.; Xiao, Y.; Li, R.; Xu, J. G.; Zhao, Y. P.; Zheng, F. K.; Guo, G. C. Color tunable and near white-light emission of two solvent-induced 2D lead(II) coordination networks based on a rigid ligand 1-tetrazole-4-imidazole-benzene. Dalton Trans. 2015, 10089-96.
13. [13]
  (13) Yang, G. S.; Liu, C. B.; Liu, H.; Robbins, J.; Zhang, Z. J.; Yin, H. S.; Wen, H. L.; Wang, Y. H. Rational assembly of Pb(II)/Cd(II)/Mn(II) coordination polymers based on flexible V-shaped dicarboxylate ligand: syntheses, helical structures and properties. J. Solid State. Chem. 2015, 225, 391-401.
14. [14]
  (14) Zhao, D.; Liang, P.; Li, Y. P.; Liu, Q. Q.; Li, W. L. Crystal structure of orthorhombic-catena-((mu(5)-adipato-kappa O-4, O':O, O')-lead(II)), C₆H₈O₄Pb. Z. Kristallogr. New Crys. Struc. 2013, 228, 343-344.
15. [15]
  (15) Li, J.; Wang, Y. H.; Song, R. F. A novel two-dimensional lead(II) coordination polymer based on dinuclear lead(II) unit containing (5-chloro-quinolin-8-yloxy) acetate. Chin. J. Struc. Chem. 2014, 33, 1488-1494.
16. [16]
  (16) Marandi, F. Syntheses, crystal structures, and properties of a new lead(II) complex involving holo- and hemidirected coordination spheres with 3, 5, 6-tris(2-pyridyl)-1, 2, 4-triazine ligand. Chin. J. Struc. Chem. 2014, 33, 1184-1190.
17. [17]
  (17) Wen, G. L.; Ma, L. F.; Chen, Y. H.; Liu, D. F. Assembly and crystal structure of a 2D lead(II) coordination polymer with 1D metal-oxygen chains. Synth. React. Inorg. Met. Org. Chem. 2014, 44, 687-691.
18. [18]
  (18) Wang, G.; Luo, M.; Lin, C.; Ye, N.; Zhou, Y.; Cheng, W. Lanthanum lead oxide hydroxide nitrates with a nonlinear optical effect. Inorg. Chem. 2014, 53, 12584-12589.
19. [19]
  (19) Su, F.; Lu, L.; Feng, S. Structure and spectroscopic properties of a three-dimensional Pb-II coordination polymer constructed from 1, 1'-biphenyl-2, 2', 4, 4'-tetracarboxylate. J. Mole. Struc. 2015, 1096, 38-42.
20. [20]
  (20) Brese, N. E.; O'Keeffe, M. Bond-valence parameters for solids. Acta Crystallogr. B 1991, 47, 192-197
1. [1]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
2. [2]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
3. [3]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
4. [4]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
5. [5]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
6. [6]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
7. [7]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
8. [8]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
9. [9]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
10. [10]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
11. [11]
  Jun Guo , Zhenbang Zhuang , Wanqiang Liu , Gang Huang . "Co-coordination force" assisted rigid-flexible coupling crystalline polymer for high-performance aqueous zinc-organic batteries. Chinese Chemical Letters, 2024, 35(9): 109803-. doi: 10.1016/j.cclet.2024.109803
12. [12]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
13. [13]
  Jianqiu Li , Yi Zhang , Songen Liu , Jie Niu , Rong Zhang , Yong Chen , Yu Liu . Cucurbit[8]uril-based non-covalent heterodimer realized NIR cell imaging through topological transformation from nanowire to nanorod. Chinese Chemical Letters, 2024, 35(10): 109645-. doi: 10.1016/j.cclet.2024.109645
14. [14]
  Shuo Li , Xinran Liu , Yongjie Zheng , Jun Ma , Shijie You , Heshan Zheng . Effective peroxydisulfate activation by CQDs-MnFe₂O₄@ZIF-8 catalyst for complementary degradation of bisphenol A by free radicals and non-radical pathways. Chinese Chemical Letters, 2024, 35(5): 108971-. doi: 10.1016/j.cclet.2023.108971
15. [15]
  Peiyan Zhu , Yanyan Yang , Hui Li , Jinhua Wang , Shiqing Li . Rh(Ⅲ)‐Catalyzed sequential ring‐retentive/‐opening [4 + 2] annulations of 2H‐imidazoles towards full‐color emissive imidazo[5,1‐a]isoquinolinium salts and AIE‐active non‐symmetric 1,1′‐biisoquinolines. Chinese Chemical Letters, 2024, 35(10): 109533-. doi: 10.1016/j.cclet.2024.109533
16. [16]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
17. [17]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
18. [18]
  Huimin Gao , Zhuochen Yu , Xuze Zhang , Xiangkun Yu , Jiyuan Xing , Youliang Zhu , Hu-Jun Qian , Zhong-Yuan Lu . A mini review of the recent progress in coarse-grained simulation of polymer systems. Chinese Journal of Structural Chemistry, 2024, 43(5): 100266-100266. doi: 10.1016/j.cjsc.2024.100266
19. [19]
  Dong Lv , Xuelei Liu , Wei Li , Qiang Zhang , Xinhong Yu , Yanchun Han . Single droplet formation by controlling the viscoelasticity of polymer solutions during inkjet printing. Chinese Chemical Letters, 2024, 35(6): 109401-. doi: 10.1016/j.cclet.2023.109401
20. [20]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(667)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A New Coordination Polymer Pb(C12H6O4): Structure Resolution of Non-merohedral Twinning Crystal

Metrics

通讯作者: 陈斌, bchen63@163.com

A New Coordination Polymer Pb(C₁₂H₆O₄): Structure Resolution of Non-merohedral Twinning Crystal