Citation: XUE Li-Ping, SHAN Li-Li, FENG Wen-Jing. Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 293-297. doi: 10.14102/j.cnki.0254-5861.2011-0845 shu

Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: XUE Li-Ping,
Received Date: 15 June 2015
Available Online: 6 September 2015
Fund Project: This work was supported by the Natural Science Foundation of China (21401097) for the financial support. (21401097)

A new cadmium(II) coordination polymer, [Cd(Hcna)₂]_n (1), was hydrothermally synthesized based on 5-(4-carboxyphenoxy)nicotinic acid (H₂cna) organic linker. X-ray single- crystal diffraction determination reveals that 1 crystallizes in the monoclinic P2₁/c space group, with a = 10.101(2), b = 7.9139(17), c = 15.627(3) Å, β = 103.364(3)°, V = 1215.4(4) Å³, Z = 2, M_r = 628.81, D_c= 1.718 Mg/m³, μ = 0.963 mm^-1, F(000) = 628, the final R = 0.0177 and wR = 0.0432 for 2263 observed reflections with I > 2σ(I). In 1, the Cd(II) cations are connected by nicotiniate units to form a two-dimensional (2D) layer, and it is further linked through benzoate units to form a three-dimensional (3D) structure. Topologically, the structure of 1 represents a 3,6-connected 3D rtl topology. Furthermore, thermal stability and photoluminescent property of 1 have also been investigated.
- cadmium coordination polymer,
- crystal structure,
- 5-(4-carboxyphenoxy)nicotinic acid,
- rtl topology,
- luminescence
1. [1]
  (1) Du, M.; Li, C.; Chen, M.; Ge, Z.; Wang, X.; Wang, L.; Liu, C. Divergent kinetic and thermodynamic hydration of a porous Cu(II) coordination polymer with exclusive CO₂ sorption selectivity. J. Am. Chem. Soc. 2014, 136, 10906-10909.
2. [2]
  (2) Xu, B.; Li, Z.; Jiang, Y.; Li, C. A luminescent Cd(II) coordination polymer constructed from isophthalic acid and 1,3-bis-(4-pyridyl)propane. Chin. J. Struct. Chem. 2015, 34, 925-930.
3. [3]
  (3) Wang, G. X.; Wu, H. X.; Li, Z. H.; Zhao, B. T. Controlled self-assembly of two coordination polymers via subtly varying bis(2-methyl imidazole) ligands: from 3-connected (6,3) net to 4-connected sql net. Chin. J. Struct. Chem. 2014, 7, 1074-1080.
4. [4]
  (4) Zhang, X.; Fan, L.; Sun, Z.; Zhang, W.; Li, D.; Dou, J.; Han, L. Syntheses, structures, and properties of a series of multidimensional metal-organic polymers based on 3,3',5,5'-biphenyltetracarboxylic acid and N-donor ancillary ligands. Cryst. Growth Des. 2013, 13, 792-803.
5. [5]
  (5) Yuan, S.; Wang, H.; Wang, D.; Lu, H.; Feng, S.; Sun, D. Reactant ratio-modulated six new copper(I)-iodide coordination complexes based on diverse [Cu_mI_m] aggregates and biimidazole linkers: syntheses, structures and temperature-dependent luminescence properties. CrystEngComm. 2013, 15, 7792-7802.
6. [6]
  (6) Wu, Y.; Li, D.; Zhao, J.; Fang, Z.; Dong, W.; Yang, G.; Wang, Y. Isomeric phenylenediacetates as modular tectons for a series of Zn^II/Cd^II coordination polymers incorporating flexible bis(imidazole) co-ligands. CrystEngComm. 2012, 14, 4745-4755.
7. [7]
  (7) Xue, L. P.; Chang, X. H.; Ma, L. F.; Wang, L. Y. Four d¹⁰metal coordination polymers based on bis(2-methyl imidazole) spacers: syntheses, interpenetrating structures and photoluminescence properties. RSC Adv. 2014, 4, 60883-60890.
8. [8]
  (8) Liu, G.; Li, X.; Xin, L.; Wang, L. Two topologically new trinodal cobalt(II) metal-organic frameworks characterized as a 1D metallic oxide and a 2D→3D penetrated porous solid. CrystEngComm. 2012, 14, 5315-5321.
9. [9]
  (9) Li, S.; Han, M.; Liu, G.; Ma, L.; Wang, L. Guest-induced single-crystal-to-single-crystal transformations of a new 4-connected 3D cadmium(II) metal-organic framework. RSC Adv. 2015, 5, 17588-17591.
10. [10]
  (10) Han, Z.; Cheng, X.; Chen, X. Effect of the size of aromatic chelate ligands on the frameworks of metal dicarboxylate polymers: from helical chains to 2-D networks. Cryst. Growth Des. 2005, 5, 695-700.
11. [11]
  (11) Yang, J.; Zhang, X.; Cheng, J.; Zhang, J.; Yao, Y. pH influence on the structural variations of 4,4'-oxydiphthalate coordination polymers. Cryst. Growth Des. 2012, 12, 333-345.
12. [12]
  (12) Xu, J.; Su, W.; Hong, M. Two lanthanide-natrium pillared-layer frameworks constructed from 4,4'-oxybis(benzoic acid) and oxalate. Inorg. Chem. Commun. 2011, 13, 1794-1797.
13. [13]
  (13) Sheldrick, G. M. SADABS, University of Göttingen, Göttingen, Germany 1997.
14. [14]
  (14) Sheldrick, G. M. SHELXS-97. Program for the Solution of Crystal Structures. University of Göttingen: Germany 1997.
15. [15]
  (15) Sheldrick, G. M. SHELXL-97. Program for the Refinement of Crystal Structures. University of Göttingen: Germany 1997.
16. [16]
  (16) Blatov, V. A.; Carlucci, L.; Ciani, G.; Proserpio, D. M. Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database. CrystEngComm. 2004, 6, 378-395.
17. [17]
  (17) Guo, Q.; Xu, C.; Zhao, B.; Jia, Y.; Hou, H.; Fan, Y. Syntheses, characterizations, and properties of five interpenetrating complexes based on 1,4-benzenedicarboxylic acid and a series of benzimidazole-based linkers. Cryst. Growth Des. 2012, 12, 5439-5446.
18. [18]
  (18) Zheng, S.; Yang, J.; Yu, X.; Chen, X.; Wong, W. Syntheses, structures, photoluminescence, and theoretical studies of d¹⁰ metal complexes of 2,2'-dihydroxy-[1,1']binaphthalenyl-3,3'-dicarboxylate. Inorg. Chem. 2004, 43, 830-838.
19. [19]
  (19) Xue, L.; Li, Z.; Li, S.; Wang, J. Synthesis, crystal structure and fluorescent property of a new one-dimensional cadmium(II) coordination polymer based on 3,4-thiophenedicarboxylic acid and 1,10-phenanthroline. Chin. J. Struct. Chem. 2013, 32, 704-708.
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沈阳化工大学材料科学与工程学院沈阳 110142