Citation: KANG Hai-Xia, FU Yu-Qin, XIN Ling-Yun, LI Gui-Lian, MA Lu-Fang, LIU Guang-Zhen. Two Coordination Polymers Containing Linear Co(II)- Trinuclear and Cu(II)-Chain Assembled from 4-Fluorocinnamic Acid and N-Donor Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 286-292. doi: 10.14102/j.cnki.0254-5861.2011-0840 shu

Two Coordination Polymers Containing Linear Co(II)- Trinuclear and Cu(II)-Chain Assembled from 4-Fluorocinnamic Acid and N-Donor Ligand

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Received Date: 9 June 2015
Available Online: 13 August 2015
Fund Project: Technology Innovation Talents in Universities of Henan Province (No. 14HASTIT017) (No. 14HASTIT017)the National Natural Science Foundation of China (No. 21571093) (No. 142300410301)

Two new coordination polymers, named {[Co₃(pfca)₆(phen)₂]·2H₂O}_n (1) and [Cu(pfca)₂(4,4'-bpy)(H₂O)]_n (2) (Hpfca = 4-fluorocinnamic acid and 4,4'-bpy = 4,4'-bipyridine), were hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. Complex 1 crystallizes in the triclinic crystal system, space group P with a = 10.939(3), b = 12.430(4), c = 13.815(4) Å, α = 78.436(3), β = 70.261(3), γ = 80.268(3)°, V = 1721.8(9) Å³, D_c = 1.508 g/cm³, M_r = 1564.06, Z = 1, F(000) = 799, μ = 0.802 mm^-1, the final R = 0.0432 and wR = 0.1015 for 13250 observed reflections with I > 2σ(I). Complex 2 is of monoclinic system, space group P2₁/c with a = 15.4985(14), b = 15.8424(14), c = 10.9528(10) Å, β = 107.1600(10)°, V = 2569.6(4) Å³, D_c = 1.468 g/cm³, M_r = 568.02, Z = 4, F(000) = 1164, μ = 0.906 mm^-1, the final R = 0.0371 and wR = 0.0842 for 18183 observed reflections with I > 2σ(I). Complex 1 features linear Co(II)-trinuclear units, which are assembled into a final 3D supramolecular structure through π…π stacking interactions and F…H weak interactions. Complex 2 consists of 1D polymeric Cu(II)-chains that are further cohered together by extensive H-bonds.
- 4-ﬂuorocinnamic acid,
- coordination polymers,
- trinuclear,
- chain,
- magnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142