Citation: SHENG Dong-Hai, DAN Wen-Yan, LUO Gen-Xiang, DENG Ming-Li. A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO₂ Adsorption and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 264-270. doi: 10.14102/j.cnki.0254-5861.2011-0838 shu

A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO₂ Adsorption and Luminescent Property

1.
a College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China;
2.
b Department of Chemistry, Fudan University, Shanghai 200433, China

Corresponding author: DENG Ming-Li,
Received Date: 5 June 2015
Available Online: 30 September 2015
Fund Project: The project was supported by the NNSFC (No. 21203032) (No. 21203032)

A three-dimensional coordination polymer, namely {[Zn₂(tzba)(dmtrz)(OH)]·3H₂O}_n (1, H₂tzba = 4-(5H-tetrazol)benzoic acid, Hdmtrz = 3,5-dimethyl-1H,1,2,4-triazole), was hydro- thermally synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic system, P2₁/c space group with a = 8.018(11), b = 21.04(3), c = 11.069(14) Å, β = 91.26(3)°, V = 1867(4) Å³, Z = 4, D_c = 1.729 g/cm³, F(000) = 984, μ = 2.614 mm^-1, R(F² > 2σ(F²)) = 0.0612 and wR(F²) = 0.1533. Topological analysis reveals that compound 1 is a (3,5)-connected structure with a Schläfli symbol of (4².6)(4².6⁵.8³), which is a rarely observed lhh topology. In addition, the CO₂ adsorption performance and luminescent property of 1 have also been studied.
- crystal structure,
- mixed ligands,
- topology
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO2 Adsorption and Luminescent Property

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通讯作者: 陈斌, bchen63@163.com

A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO₂ Adsorption and Luminescent Property