Citation: ZHANG Hui, YUAN Guo-Jun, LIU Shao-Xian, DUAN Hai-Bao. Two [Ni(dmit)₂]^- Compounds Showing Layered and Chain Alignments: Crystal Structures and Magnetic Properties[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 271-278. doi: 10.14102/j.cnki.0254-5861.2011-0833 shu

Two [Ni(dmit)₂]^- Compounds Showing Layered and Chain Alignments: Crystal Structures and Magnetic Properties

1.
a School of Environmental Science, Nanjing Xiaozhuang College, Nanjing 211171, China;
2.
b School of Chemical and Engineering, Anhui Huangshan University, Anhui 245021, China

Received Date: 3 June 2015
Available Online: 19 August 2015
Fund Project:

Two metal-dithiolene compounds with a formula of [4-ClBz-1-APy][Ni(dmit)₂] (1) and [4-NO₂Bz-1-APy][Ni(dmit)₂] (2, 4-ClBz-1-APy = 1-N-(4'-chlorobenzyl)pyridinium, 4-NO₂Bz- 1-APy = 1-N-(4'-nitrobenzyl)pyridinium, dmit^2- = l,3-dithiole-2-thione-4,5-dithiolate) were synthesized and characterized. Two compounds crystallize in triclinic space group P1 and P1, respectively, but with different cell parameters and packing structures. The [Ni(dmit)₂]^- anions and cations of 1 form mixed column stacks along the a axis and alternately layered alignments in the crystal of 2, which are parallel to the crystallographic (110) plane. Two compounds show a similar magnetic behavior, the magnetic exchange natures are mainly antiferromagnetic, and the magnetic susceptibility data can be fitted to the simple Curie-Weiss law. For 1 and 2, the fitted Curie constants are much less than the spin-only value expected for an S = 1/2 system, and the fitted Weiss constants marking magnetic interaction are also very smaller. This fact implies that the weak Currie- Weiss-type paramagnetism is not the intrinsic characteristics of two compounds.
- metal-bis-dithiolene compound,
- crystal structure,
- magnetic property
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Two [Ni(dmit)2]- Compounds Showing Layered and Chain Alignments: Crystal Structures and Magnetic Properties

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通讯作者: 陈斌, bchen63@163.com

Two [Ni(dmit)₂]^- Compounds Showing Layered and Chain Alignments: Crystal Structures and Magnetic Properties