Citation: LI Jun-Ye, SUN Hong-Jian. Synthesis, Structure and Properties of a Novel Nickel(Ⅱ) Chloride Complex Supported by Phosphine Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(11): 1735-1741. doi: 10.14102/j.cnki.0254-5861.2011-0739 shu

Synthesis, Structure and Properties of a Novel Nickel(Ⅱ) Chloride Complex Supported by Phosphine Ligands

LI Jun-Ye ^a ,
SUN Hong-Jian ^b,,

a.
a. Department of Pharmaceutical Science and Technology, Heze University, Heze 274000, China;
b.
b. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250199, China

Corresponding author: SUN Hong-Jian,
Received Date: 27 March 2015
Available Online: 8 June 2015
Fund Project:

The C-Cl bond of N-(2-chlorophenyl)acetamide (1) was successfully activated by tetrakis(trimethylphosphine)nickel(0). The four-coordinate nickel(Ⅱ) chloride complex trans-[(C₆H₄NHC(=O)Me)Ni(PMe₃)₂Cl] (2) as a C-Cl bond activation product was obtained without coordination of the amide group. Phosphonium salt Cl-[Me₃P⁺-ortho-C₆H₄NHC(=O)Me] (3) was isolated by reacting complex 2 as a starting material under 1 bar of CO at room temperature. The molecular and crystal structures of 2 were determined by single-crystal X-ray diffraction.
- C-Cl activation,
- N-(2-chlorophenyl)acetamide,
- phosphonium salt
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