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Citation: LI Xiu-Ying, WANG Lu-Yao, SONG Ning, MA Bo-Nan, ZHANG Xing-Jing, CHE Guang-Bo. Hydrothermal Syntheses and Crystal Structures of Cd(Ⅱ) and Cu(Ⅱ) Complexes Constructed with 1,3,5-Benzenetricarboxylic Acid and Dipyrido[3,2-a:2',3'-c]phenazine Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(11): 1709-1716. doi: 10.14102/j.cnki.0254-5861.2011-0730 shu

Hydrothermal Syntheses and Crystal Structures of Cd(Ⅱ) and Cu(Ⅱ) Complexes Constructed with 1,3,5-Benzenetricarboxylic Acid and Dipyrido[3,2-a:2',3'-c]phenazine Ligands

a.
a. College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China;
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b. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Chinese Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China;
c.
c. College of Animal Science & Technology, Changchun University of Science and Technology, Shuangyang, Jilin 130600, China

Received Date: 2 March 2015
Available Online: 8 July 2015
Fund Project: Supported by the Program for New Century Excellent Talents in University (NCET-10-0176) (NCET-10-0176) NNSFC (21407064) (21407064) NSF of Jilin Province (20130521019JH, 201215219) (20130521019JH, 201215219) the Education Bureau of Jilin Province ([2014]152) ([2014]152)

Two novel coordination compounds, [Cd₂(HBTC)₂(DPPZ)₂(H₂O)₃]·2H₂O (1) and [Cu₂(HBTC)₂(DPPZ)₂(H₂O)]_n (2) based on 1,3,5-benzenetricarboxylic acid (H₃BTC) and dipyrido[3,2-a:2',3'-c]phenazine (DPPZ) ligands, have been constructed under hydrothermal conditions. Two complexes are characterized by elemental analysis, IR and single-crystal X-ray diffraction. Structural analyses show that both complexes 1 and 2 present the three-dimensional supramolecular structures. In addition, two complexes exhibit luminescence property.
- cadmium(Ⅱ) complex,
- copper(Ⅱ) complex,
- 1,3,5-benzenetricaboxylic acid,
- dipyrido[3,2-a:2',3'-c]phenazine,
- crystal structure
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