Citation: HE Su-Hua, LIN Zi-Xiong, Muhammad Ali Khan, LIU Peng-Fei, CHEN Ling, WU Li-Ming. Thermoelectric Properties of Ni-substituted Polycrystalline In₄Se₃[J]. Chinese Journal of Structural Chemistry, ;2015, 34(8): 1217-1223. doi: 10.14102/j.cnki.0254-5861.2011-0719 shu

Thermoelectric Properties of Ni-substituted Polycrystalline In₄Se₃

a.
a. College of Chemistry, Fuzhou University, Fuzhou 350002, China;
b.
b. Key Laboratory of Design and Assembly of Functional nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: WU Li-Ming,
Received Date: 17 March 2015
Available Online: 15 April 2015
Fund Project:

Thermoelectric (TE) materials can convert directly low-grade heat energy to electricity, and vice versa, which is highly expected to play an important role in the future energy management. The application practice demands efficient TE materials made of non-toxic and inexpensive components. Herein, we report a Ni substituted polycrystalline n-type bulk material In_4-xNi_xSe₃ (x=0~0.1). Based on density functional theory calculation, Ni tends to substitute at the In3 site in the In₄Se₃, which causes a monotonous unit cell volume reduction. At x=0.01, Ni substitution results in a sharp decrease in the carrier concentration (n_e) in comparison with that of pure In₄Se₃, and then n_e increases with the increase of Ni concentration. Ni substitution leads to a performance enhancement from 0.6 for pure In₄Se₃ to an optimum ZT value of 0.8 at 450℃.
- In₄Se₃,
- TE materials,
- Ni substitution,
- n_e
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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