Citation: ZHOU Bao-Han, HUA Yun-Tao, XU Bao-Ming, MA Li, HU Jia-Wen, LIU Zhao-Jie. Syntheses, Crystal Structures and Antifungal Activities of Two Compounds Containing Pyrazole and Pyrethroid Units[J]. Chinese Journal of Structural Chemistry, ;2015, 34(8): 1231-1237. doi: 10.14102/j.cnki.0254-5861.2011-0717 shu

Syntheses, Crystal Structures and Antifungal Activities of Two Compounds Containing Pyrazole and Pyrethroid Units

a.
a. School of Chemistry and Chemical Engineering, Light Industry Division, Hubei University of Technology, Wuhan 430068, China;
b.
b. Key Lab of Pesticide and Chemical Biology, Ministry of Education, Central China Normal University, Wuhan 430079, China

Received Date: 16 March 2015
Available Online: 18 June 2015
Fund Project: National Natural Science Foundation of China (No. 21272086) (No. ZRY0981)

Compounds 1 (C₁₅H₁₇ClF₃N₃O₃, M_r=379) and 2 (C₁₄H₁₄ClF₃N₄OS, M_r=378) have been synthesized and their crystal structures were determined by single-crystal X-ray diffraction. Crystal 1 belongs to the triclinic system, space group P1 with a=6.0223(19), b=9.324(3), c=15.936(5)Å, α=80.687(5), β=87.289(5), γ=86.097(5)°, V=880.4(5)Å³, Z=2, D_c=1.433 g/cm³, μ(MoKα)=0.266 mm^-1, F(000)=392, R=0.0861 and wR=0.1999 for 2022 observed reflections with I>2σ(I). Crystal 2 belongs to the triclinic system, space group P1 with a=7.7029(15), b=8.3371(16), c=14.410(3)Å, α=100.672(3), β=103.168(3), γ=98.726(3)°, V=876.1(3)Å³, Z=2, D_c=1.451 g/cm³, μ(MoKα)=0.379 mm^-1, F(000)=388, R=0.0672 and wR=0.2105 for 2725 observed reflections with I>2σ(I). Although the two compounds are similar with the same pyrazole and pyrethroid units, X-ray analysis reveals that their structures are completely different.
- pyrazole,
- crystal structures,
- synthesis,
- antifungal activities
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