Citation: KONG Zhi-Guo, GUO Sheng-Nan, HE Gui-Yuan, LI Xin-Hang, JIAO Yu-Qi, WANG Xiu-Yan. Crystal Structure and Luminescence of a New Two-dimensional Sr(Ⅱ) Coordination Polymer Based on 3,5-Dinitro-salicylic Acid and 1,10-Phenanthroline[J]. Chinese Journal of Structural Chemistry, ;2015, 34(8): 1295-1299. doi: 10.14102/j.cnki.0254-5861.2011-0692 shu

Crystal Structure and Luminescence of a New Two-dimensional Sr(Ⅱ) Coordination Polymer Based on 3,5-Dinitro-salicylic Acid and 1,10-Phenanthroline

KONG Zhi-Guo ^a,b ,
GUO Sheng-Nan ^a,b ,
HE Gui-Yuan ^a,b ,
LI Xin-Hang ^a,b ,
JIAO Yu-Qi ^a,b ,
WANG Xiu-Yan ^a,b,,

a.
a. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China;
b.
b. Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: WANG Xiu-Yan,
Received Date: 16 February 2015
Available Online: 14 April 2015
Fund Project: Supported by the Institute Foundation of Siping City (No. 2013036) (No. 2013036)

In this work, we report a new two-dimensional Sr(Ⅱ) coordination polymer, namely, [Sr(L)(phen)(H₂O)] (1), based on 3,5-dinitro-salicylic acid (H₂L) and 1,10-phenanthroline (phen). It crystallizes in monoclinic, space group P2₁/c with a=15.479(3), b=9.4020(19), c=13.884(3)Å, β=103.76(3)°, V=1962.5(7)Å³, Z=4, C₁₉H₁₂SrN₄O₈, M_r=511.95, D_c=1.733 g/cm³, F(000)=1024, μ(MoKa)=2.805 mm^-1, R=0.0411 and wR=0.1069. In 1, each L anion bridges three Sr(Ⅱ) atoms by using carboxylate and hydroxyl groups, yielding a two-dimensional layer structure. The phen ligands are alternately attached to both sides of the layer. The π-π stacking between L and phen in the same layer and hydrogen-bonding interactions between water molecule and carboxylate oxygen atom play an important role in stabilizing the layer structure of 1. The solid state luminescent property of 1 was also studied at room temperature.
- crystal structure,
- coordination polymer,
- 3,5-dinitro-salicylic acid,
- luminescent property
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