Citation: WANG Rong-Ming, ZHANG Ming-Hui, LIU Xiao-Qing, LIU Xiao-Bin, WANG Wen, SUN Dao-Feng. Synthesis, Crystal Structure and Luminescence of a Trinuclear Magnesium Coordination Polymer Based on a Triangle Flexible Carboxylic Ligand[J]. Chinese Journal of Structural Chemistry, ;2015, 34(8): 1288-1294. doi: 10.14102/j.cnki.0254-5861.2011-0691 shu

Synthesis, Crystal Structure and Luminescence of a Trinuclear Magnesium Coordination Polymer Based on a Triangle Flexible Carboxylic Ligand

1.
College of Science, China University of Petroleum(East China), Qingdao, Shandong 266580, China

Received Date: 2 March 2015
Available Online: 14 May 2015
Fund Project: Supported by the National Natural Science Foundation of China (No. 21371179) (No. 21371179)

A novel two-dimensional metal organic coordination compound based on flexible 1,3,5-tri(4-carboxyphenoxy)benzene (H₃TCPB), {[Mg_1.5(TCPB)(DMF)(H₂O)]·(DMF)}_n (1), has been prepared and structurally characterized by single-crystal X-ray diffraction, TGA, and PXRD measurements. Complex 1 crystalizes in triclinic, space group P1 with a=10.2521(6), b=11.0974(7), c=16.1113(9)Å, C₃₃H₃₁Mg_1.5N₂O₁₂, M_r=684.06, V=1669.46(17)Å³, Z=2, D_c=1.361 g·cm^-3, μ=0.129 mm^-1, F(000)=714, 3.06≤θ≤25°, λMoKα)=0.71073Å, T=273(2) K, the final R=0.0386, wR=0.0892 and S=1.031. X-ray diffraction analysis reveals that complex 1 possesses a two-dimensional framework constructed by trinuclear Mg SBUs and three-connected TCPB^3- linker. In addition, the solid state luminescent property of complex 1 was also investigated at room temperature.
- crystal structure,
- two-dimensional framework,
- fluorescence,
- magnesium
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