Citation: LI Fu-An, ZHAO Xiao-Jun, YANG Wei-Chun, LI Song-Tian. A Co(Ⅱ) Coordinated Polymer with 2-Fold Interpenetration 3D Architecture Based on 5-(Imidazol-1-ylmethyl)isophthalate: Hydrothermal Synthesis, Crystal Structure and Properties[J]. Chinese Journal of Structural Chemistry, ;2015, 34(8): 1281-1287. doi: 10.14102/j.cnki.0254-5861.2011-0653 shu

A Co(Ⅱ) Coordinated Polymer with 2-Fold Interpenetration 3D Architecture Based on 5-(Imidazol-1-ylmethyl)isophthalate: Hydrothermal Synthesis, Crystal Structure and Properties

1.
College of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan 467000, China

Received Date: 26 January 2015
Available Online: 26 March 2015
Fund Project: We are thankful for the financial support from Education Chamber of Henan Province (No. 15A150068) (No. 15A150068)Key Laboratory of Applied Chemistry of Pingdingshan University (No. 201201) (No. 201201)

One cobalt coordinated polymer with 2-fold parallel interpenetration 3D architecture based on flexible 5-(imidazol-1-ylmethyl)isophthalate (L^2-) as a main ligand and 4,4'-bipyridine (bpy) as a nitrogen-containing ancillary ligand, {[CoL(bpy)_0.5(H₂O)₃]₂}_n (1), has been obtained under hydrothermal conditions and characterized by elemental analysis, powder X-ray diffraction (PXRD), IR spectra, Uv/vis spectra, thermal gravimetric analyses (TGA) and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group C2/c with a=26.323(4), b=14.696(2), c=26.630(4)Å, β=157.747(4)°, V=3901.2(1)Å³, Z=8, M_r=435.27, D_c=1.480 g/cm³, μ=0.923 mm^-1, R_int=0.0900, F(000)=1792, the final R=0.0722 and wR=0.0946 for 3641 observed reflections (I>2σ(I)). Complex 1 exhibits a two-fold interpenetration 3D framework. As a single net of the 2-fold interpenetration structure, the L^2- anion of complex 1, as a bridging ligand, connects the Co(Ⅱ) ion to form two-dimensional layers (Co₃L₃)_n which are further linked to build a three-dimensional framework by bpy ligand.
- cobalt,
- 5-(imidazol-1-ylmethyl)isophthalic acid,
- PXRD,
- coordinated polymer
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